Atomic order in the spinel structure – a group-theoretical analysis

Talanov, V.M.; Shirokov, V.B.

doi:10.1107/S2053273313027605

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Figure 7
Calculated low-symmetry anion-ordered spinel structure with space group $[F{\overline 4}3m]$ and structural formula A^4aB^16e₄X^16e₄X′^16e₄. Atom presentation of the ordered spinel structure (a), tetrahedra in the ordered spinel structure (b), B^16e metallic tetrahedra (c). A substance with composition Re₄As₆S₃ has a similar structure. In this structure there are Re₄ clusters (Besnard et al., 2003

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ISSN: 2053-2733

Volume 70| Part 1| December 2014| Pages 49-63

doi:10.1107/S2053273313027605

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