Acta Crystallographica Section B

Structural Science

Volume 53, Part 6 (December 1997)

research papers

Acta Cryst. (1997). B53, 895-903    [doi:10.1107/S0108768197008331]

Three New Polymorphic Forms of Molybdenum Pentachloride

J. Beck and F. Wolf

Synopsis: Three new polymorphic modifications of MoCl₅ have been obtained as single crystals by solvothermal syntheses using CCl₄ and SbCl₅ as solvents. All structures consist of double octahedral Mo₂Cl₁₀ molecules and are derived from the closest packings of Cl atoms with different stacking sequences.

	Structure factor file (CIF format) (52.8 kbytes) Contains datablock b_mocl5
	Structure factor file (CIF format) (74.2 kbytes) Contains datablock c_mocl5
	Structure factor file (CIF format) (183.8 kbytes) Contains datablock d_mocl5

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