Acta Crystallographica Section B

Structural Science

Volume 54, Part 3 (June 1998)


research papers



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Acta Cryst. (1998). B54, 211-220    [doi:10.1107/S0108768197013177]

Monoclinic and Hexagonal Nepheline Structures of (Na3/4/K1/4)AlGeO4

R. P. Hammond and J. Barbier

Synopsis: Hexagonal (Na3/4K1/4)AlGeO4 is isostructural with the mineral nepheline, (Na3/4K1/4)AlSiO4, with a similar split oxygen position and a cation deficiency on the potassium site. In contrast, the alkali sites are fully occupied in the structure of monoclinic (Na3/4K1/4)AlGeO4 and the lower unit-cell symmetry eliminates the oxygen disorder.


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