Acta Crystallographica Section B

Structural Science

Volume 57, Part 3 (June 2001)

Acta Cryst. (2001). B57, 394-398 [doi:10.1107/S010876810002108X]

Inclusion compounds of binaphthol with picolines: structures, selectivity and kinetics of desolvation

L. R. Nassimbeni and H. Su

Abstract: The crystal structures of the inclusion compounds formed between the host 2,2'-dihydroxy-1,1'-binaphthyl and the three picoline isomers have been elucidated and their lattice energies calculated. The selectivities of enclathration by the host have been measured by competition experiments. The thermal stabilities and activation energies of desolvation of the compounds have been determined. The kinetics of desolvation are correlated to the structures.

Online 25 May 2001


	Structure factor file (CIF format) (13.7 kbytes) Contains datablock BNP2P

	Structure factor file (CIF format) (19.4 kbytes) Contains datablock BNP3P

	Structure factor file (CIF format) (20.6 kbytes) Contains datablock BNP4P

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