Acta Crystallographica Section B

Structural Science

Volume 57, Part 4 (August 2001)



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Acta Cryst. (2001). B57, 517-519    [doi:10.1107/S0108768101007807]

Correction of the space group of [Ni(bipy)2(ONO2)2]·2(pyrene)

F. H. Herbstein

Abstract: The crystal structure of [Ni(bipy)2(ONO2)2]·2(pyrene), poly[[[bis(nitrato-O)nickel(II)]bis([bold mu]-4,4'-bipyridyl-N,N'] bis(pyrene)], was originally reported in space group Pn [Biradha et al. (1999). Chem. Commun. pp. 1327-1328]. Reasons are given for changing the space group to P21/n. Consequently, incorrect descriptions of the title compound in the literature must be altered. In particular, the structure is not polar. It is further contended that description in terms of `complementary, interpenetrating covalent and noncovalent two-dimensional networks' is misleading as the `noncovalent network' (of pyrenes) has geometrical but not physical significance. The title compound is a typical host-guest inclusion complex.

Online 24 July 2001


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