Acta Cryst. (2006). B62, 109-117 [ doi:10.1107/S0108768105038267 ]
Abstract: 3,5-Dichloro-4-hydroxybenzonitrile and its solvates with benzene and xylene assemble in chain-like arrangements held together by OH
NC interactions. Two polymorphs each of the corresponding dibromo and diiodo compounds form similar chains which are then bound together by X
X interactions to form approximately planar sheets. These sheets are essentially identical in all four of the bromo and iodo compounds and have approximate p2gg two-dimensional symmetry. These four compounds form an extreme example of two-dimensional isostructuality. The polymorphs differ in the stacking arrangements. One of the Br polymorphs is isostructural with one of the I polymorphs.
Keywords: polymorphism; isostructurality; stacking arrangements.
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![]() ![]() Structure factor file (CIF format) (196.6 kbytes) | |
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