Acta Crystallographica Section B

Structural Science, Crystal Engineering and Materials

Volume 69, Part 6 (December 2013)

research papers

Acta Cryst. (2013). B69, 563-569    [ doi:10.1107/S2052519213025268 ]

Cationic radii from structures of extremely compressed solids

S. S. Batsanov

Abstract: The cationic radii of metals are derived from the compressibility of solids assuming that extreme compression of metals leads to direct contacts between cations (= atomic cores). In an extremely compressed binary compound the heteronuclear separations are equal to the sum of the cationic radius of the metal and the covalent radius of the nonmetal.

Keywords: high pressures; cationic radii; equations of state; compressed solids.

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