Acta Crystallographica Section C

Crystal Structure Communications

Volume 51, Part 1 (January 1995)

Cover illustration: Diethyl Methano-C60-fullerne-61,61-dicarboxylate Chloroform Solvate at 193 K, C60C(CO2C2H5)2. CHCl3, see Paulus & Bingel, pages 143-146. The displacement ellipsoids are shown at the 50% probability level.

• editorial
• inorganic compounds
• metal-organic compounds
• organic compounds
• international union of crystallography

editorial

 

Editorial

S.R. Hall

inorganic compounds

 

Lead Diselenite

M. Koskenlinna and J. Valkonen

Synopsis: PbSe₂O₅ forms a three-dimensional network with each diselenite ion bridging five Pb ions and with five diselenite ions grouped around each Pb ion. The coordination around Pb comprises six O atoms forming a dented one-sided octahedron with 2 + 2 O atoms near Pb but with longer Pb-O distances.

Formula: PbSe₂O₅

 

Lithium Perbromate Monohydrate at 296 and 173 K

A. C. Blackburn and R. E. Gerkin

Synopsis: LiBrO₄.H₂ZO, whose found to be isomorphic with NaBrO₄.H₂O and NaClO₄.H₂O. Dynamic disordering of the H atoms (detailed by magnetic resonance methods for NaClO₄.H₂O) is found to be significant in the title salt.

Formula: LiBrO₄.H₂O

metal-organic compounds

 

Sodium Bis[1,2-ethanediolato(2-)](hydroxyethoxo)silicate(1-) Acetonitrile Solvate, Na[Si(C₂H₄O₂)₂(C₂H₅O₂)].0.25C₂H₃N

G. J. Gainsford, T. Kemmitt and N. B. Milestone

Formula: Na[Si(C₂H₄O₂)₂(C₂H₅O₂)].0.25C₂H₃N

 

Chlorotris(trimethylsilylcyclopentadienyl)zirconium

W. Lukens

Formula: [ZrCl(C₈H₁₃Si)₃]

 

Oxobis(2,4-pentanedionato)vanadium(IV), a Redetermination

E. Shuter, S. J. Rettig and C. Orvig

Formula: [VO(C₅H₇O₂)₂]

 

A Tetranuclear Butterfly Cluster of Molybdenum, [PPh₄]₂[Mo₄I₁₁]

J. C. Gordon and R. Poli

Formula: (C₂₄H₂₀P)₂[Mo₄I₁₁]

 

Trichloro(1,4,7-tri-n-butyl-1,4,7-triazacyclononane-N,N',N'')chromium

F.-J. Wu, G. P. Stahly, F. R. Fronczek and S. F. Watkins

Formula: [CrCl₃(C₁₈H₃₉N₃)]

 

cis-trans-[{N₃P₃Cl₄(C₆H₅)(PPh₂)}Mn(CO)₂(bipy){P(OPh)₃}]PF₆. A Cationic Manganese-Carbonyl Complex with a Phosphazenylphosphine Ligand

G. A. Carriedo, L. Fernández, P. Gómez, S. García-Granda and A. M. Velázquez

Formula: [Mn(C₁₈H₁₅O₃P)(C₁₀H₈N₂)(C₁₈H₁₅Cl₄N₃P₄)(CO)₂]PF₆

 

[MoH₄(dppe)₂].thf (dppe = Ph₂PCH₂CH₂PPh₂; thf = Tetrahydrofuran)

A. J. L. Pombeiro, A. Hills, D. L. Hughes and R. L. Richards

Formula: [MoH₄(C₂₆H₂₄P₂)₂].C₄H₈O

 

Hexafluorophosphate Salts of Cyclopentadienyliron(II) Complexes of Dibenzodioxin and 1-Methyldibenzodioxin

A. Piórko, S. Christie and M. J. Zaworotko

Formula: [Fe(C₅H₅)(C₁₂H₈O₂)]PF₆ and[Fe(C₅H₅)(C₁₃H₁₀O₂)]PF₆.0.5C₄H₁₀O

 

[Au₂Cl₂(fdpp)₃], a Structural Intermediate in the Assembly of Gold-Phosphine Chain Polymers

A. Houlton, D. M. P. Mingos, D. M. Murphy and D. J. Williams

Formula: [Au₂Fe₃Cl₂(C₁₇H₁₄P)₆].2CH₂Cl₂

 

Disodium -(Ethylenediaminetetraacetato-N,O,O':N',O'',O''')-di--oxo-bis[oxomolybdate(V)](Mo-Mo) Tetrahydrate

K. Mukherjee, P. Roychowdhury, K. Roy, D. Mukherjee and M. Kusunoki

Formula: 2Na[Mo₂O₄(C₁₀H₁₂N₂O₈)].4H₂O

 

[{-C(OC₂H₅)}(CO)₄Fe₂C{(OC₂H₅)(p-CF₃C₆H₄)(-C₇H₇)}]

J. Chen, P.-J. Zheng, Y. Yu and J.-B. Chen

Formula: [Fe₂(C₁₇H₁₆F₃O)(C₃H₅O)(CO)₄]

 

Hexaaquanickel(II) D-Camphor-10-sulfonate

W. Henderson and B. K. Nicholson

Formula: [Ni(H₂O)₆]2C₁₀H₁₅O₄S

 

trans-Dichlorotetrakis(pyridine-N)ruthenium(II)

M. R. J. Elsegood and D. A. Tocher

Formula: [RuCl₂(C₅H₅N)₄]

 

(-H)(-OH)Os₃(CO)₁₀

D. W. Knoeppel, J.-H. Chung and S. G. Shore

Formula: [Os₃H(OH)(CO)₁₀]

 

Low-Temperature Structures of [py₂H]⁺[Co(CO)₄]^- (py = Pyridine) and [(tmen)H]⁺[Co(CO)₄]^- (tmen = N,N,N',N'-Tetramethylethylenediamine)

L. Brammer and D. Zhao

Formula: [(C₅H₅N)₂H][Co(CO)₄] and (C₆H₁₇N₂)[Co(CO)₄]

 

[N,N-Bis(2-aminoethyl)-N'-(2-aminoethylidene)ethane-1,2-diamine]chlorocobalt(III) Perchlorate

M. Giannos, G. D. Fallon and L. Spiccia

Formula: [CoCl(C₈H₂₁N₅)]2ClO₄

 

Chloro[(1-methyl-2-imidazolyl-N³-methyl)-bis(2-pyridyl-N-methyl)amine-N]copper(II) Hexafluorophosphate, [CuCl(C₁₇H₁₉N₅)]PF₆

J. Wang, M. S. Mashuta, J. F. Richardson and R. M. Buchanan

Formula: [CuCl(C₁₇H₁₉N₅)]PF₆

 

Folding onto Copper(II) of a Flexible Bis-Chelating 4-Acyl-pyrazol-5-olate

G. J. Goetz-Grandmont, A. Tayeb, D. Matt, J.-P. Brunette and L. Toupet

Formula: [Cu(C₃₀H₃₂N₄O₄)]

 

Triruthenium Alkylidyne Cluster Complexes [H₂Ru₃(CO)₉(₃-CX)] (X = Pyridine, 4-Ethylpyridine)

W.-T. Wong and W.-Y. Wong

Formula: [Ru₃H₂(C₆H₅N)(CO)₉] and [Ru₃H₂(C₈H₉N)(CO)₉]

 

Silver Oxalate, 2Ag⁺.C₂O₄^2-

D. Yu. Naumov, A. V. Virovets, N. V. Podberezskaya and E. V. Boldyreva

Formula: 2Ag⁺.C₂O₄^2-

 

Diazidobis(2,2'-bipyridine)nickel(II) Monohydrate

M. K. Urtiaga, M. I. Arriortua, I. G. De Muro and R. Cortes

Formula: [Ni(N₃)₂(C₁₀H₈N₂)₂].H₂O

 

Zinc(II) Complex of Urocanic Acid

N. Okabe and Y. Sasaki

Formula: [Zn(C₆H₅N₂O₂)₂(H₂O)₄]

 

Tris(triphenyltin)borate

G. Ferguson, T. R. Spalding and A. T. O'Dowd

Formula: [Sn₃(BO₃)(C₆H₅)₉]

 

Chlorobis(N,N-diethyldithiocarbamato)(vinyl)tin(IV)

V. Vrábel, E. Kellö, J. Holecek, J. Sivý and J. Lokaj

Formula: [SnCl(C₂H₃)(C₅H₁₀NS₂)₂]

 

2,4'-Bithiazole and Bis(2,4'-bithiazole)bis(dimethyl sulfoxide)copper(II) Diperchlorate

N. Benali-Cherif, M. Pierrot, C. Baudrion and J. P. Aune

Formula: C₆H₄N₂S₂ and [Cu(C₆H₄N₂S₂)₂(C₂H₆OS)₂](ClO₄)₂

organic compounds

 

5,5'-Bithiazole and 2,5'-Bithiazole

N. Benali-Cherif, M. Pierrot, C. Baudrion and J. P. Aune

Formula: Two isomers of C₆H₄N₂S₂

 

1-(Phenylsulfonyl)-2-[1-(phenylsulfonyl)-2-(3,4,5-trimethoxyphenyl)ethyl]indole

J. Seetharaman and S. S. Rajan

Formula: C₃₁H₂₉NO₇S₂

 

A Macrobicyclic Thiophosphonamide Polyether Ligand

L. Van Oostenryck, B. Tinant, J.-P. Declercq and J.-P. Dutasta

Formula: Two crystal forms of C₂₉H₃₅N₂O₅PS

 

(1'R,2S,3R)-2-Hydroxy-2-(1-hydroxyethyl)-3-methyl--butyrolactone

J. Kopf and S. Schulz

Formula: C₇H₁₂O₄

 

A Chiral Bicyclic 1-Acetoxy Phosphonamide

V. J. Blazis, K. J. Koeller, N. P. Rath and C. D. Spilling

Formula: C₂₃H₄₅N₂O₃P

 

2,4,6-Trihexyl-1,3,5-trithiane

N. Veldman, A. L. Spek, J. J. H. Edema and R. M. Kellogg

Formula: C₂₁H₄₂S₃

 

(3aS,3bR,6R,7aR)-2-Benzyl-1,2,3a,3b,4,7a-hexahydro-6-phenyl-3,5-dioxa-2,6a-diazacyclopenta[a]pentalen-7-one

A. Chiaroni, A. Deyine, D. Griffard-Brunet, N. Langlois and C. Riche

Formula: C₂₀H₂₀N₂O₃

 

(5S,SS)-7-Methyl-8-p-toluenesulfinyl-1,6-dioxaspiro[4.5]dec-7-ene

R. Retoux, P. Hayes and C. Maignan

Formula: C₁₆H₂₀O₃S

 

The Diels-Alder Adduct of an Enantiopure 2-Sulfinyldiene and Maleimide: (1S,2R,3S,SR)-3-Methyl-5-p-toluenesulfinylcyclohex-4-en-1,2-dicarboximide

P. Gosselin, E. Bonfand, C. Maignan and R. Retoux

Formula: C₁₆H₁₇NO₃S

 

5-Ethyl-2'-deoxycytidine, C₁₁H₁₇N₃O₄

S. Napper, A. L. Stuart, S. V. P. Kumar, V. S. Gupta and L. T. J. Delbaere

Formula: C₁₁H₁₇N₃O₄

 

Two Centrosymmetric Conjugated Nitrones of the Diazabutadiene System

P. K. Olszewski and K. Stadnicka

Formula: C₂₁H₁₈N₂O₂ and C₂₂H₂₁N₃O

 

1-Phenyl-3-(3,4,5-trimethoxyphenyl)-1,3-propanedione

J.-C. Wallet, E. Molins and C. Miravitlles

Formula: C₁₈H₁₈O₅

 

[1-(Ethoxycarbonyl)-1-cyclopentyl]triphenylphosphonium Bromide, [(C₆H₅)₃PC(C₄H₈)(COOC₂H₅)]Br

D. Boys, R. Araya-Maturana, O. González and V. Manríquez

Formula: C₂₆H₂₈O₂P⁺.Br^-

 

7-Dimethylaminocyclopenta[c]coumarin, in Two Polymorphic Forms

J. P. Jasinski and R. C. Woudenberg

Formula: Two polymorphs of C₁₄H₁₅NO₂

 

2-[(3,4-Dimethoxybenzyl)(p-toluenesulfonyl)amino]-2-phenylethanol

M. I. Arriortua, M. K. Urtiaga, D. Badía, E. Domínguez, A. M. González Cameno and X. Solans

Formula: C₂₄H₂₇NO₅S

 

Methyl (3R*,4R*)-4-Hydroxy-3-phenyl-2-(p-toluenesulfonyl)-1,2,3,4-tetrahydro-4-isoquinolinylacetate

M. K. Urtiaga, D. Badía, E. Domínguez, A. M. González-Cameno, J. M. Amigó, M. M. Reventós and T. Debaerdemaeker

Formula: C₂₅H₂₅NO₅S

 

2-Hydroxymethylbenzimidazole

A. Aubry, A. Brembilla, V. Faivre and P. Lochon

Formula: C₈H₈N₂O

 

Two Isomeric Sulfites of 10-Pinane-2,3-diol

D. G. Hellier and M. Motevalli

Formula: Two isomers of C₁₀H₁₆O₃S

 

7,8-Epoxyfriedelane

I. Dey and A. Banerjee

Formula: C₃₀H₅₀O

 

Piperidine Nitroxide Radicals with Heterocyclic Ring Substituents. 4-Hydroxy-2,2,6,6-tetramethyl-4-(2-pyridylmethyl 1-oxide)piperidine 1-Oxide

T. A. Olszak, P. H. Sobczynski, A. M. Brzozowski, M. J. Grabowski and K. Gwozdzinski

Formula: C₁₅H₂₃N₂O₃

 

2'-Hydroxy-2-methoxychalcone

J.-C. Wallet, E. Molins and C. Miravitlles

Formula: C₁₆H₁₄O₃

 

Cyclohexanecarbohydroxamic Acid

I. K. Larsen and P. Trickey

Formula: C₇H₁₃NO₂

 

Securinine, an Alkaloid from Fluggea virosa

P. Luger, M. Weber, N. X. Dung, P. T. Ky and P. K. Long

Formula: C₁₃H₁₅NO₂

 

4,5-Dicyclohexyl-1,3,2-dioxathiolane 2-Oxide, C₁₄H₂₄O₃S

D. G. Hellier and M. Motevalli

Formula: C₁₄H₂₄O₃S

 

5ar-p-Tolyl-6at,7t,8,9,10t,10at-hexahydro-11H,13H-7,10-methano[1,3]benzoxazino[2,3-b][1,3]benzoxazin-13-one

A. Kapor, G. Stájer, S. Frimpong-Manso and G. Bernáth

Formula: C₂₃H₂₃NO₃

 

Homochiral Methyl (2R,3S)-3-Bromo-2-chloro-3-phenylpropanoate

J. P. Shaw, E. W. Tan and A. G. Blackman

Formula: C₁₀H₁₀BrClO₂

 

(13-Methyl-1,4,7,8,13,13b-hexahydro[1',2']oxazepino[2',3':1,2]pyrido[3,4-b]indol-1-yl)methanol and its Unusual Packing Style

H. Ohishi, Y. Sakamoto, S. Harusawa, R. Yoneda and T. Kurihara

Formula: C₁₇H₂₀N₂O₂

 

2-[5-(Diethylaminosulfonyl)-2-methoxyphenylhydrazono]-3-oxo-N-phenylbutyramide

J. Fawcett, R. D. W. Kemmitt, D. R. Russell, O. Serindag, B. Guzel and S. Serin

Formula: C₂₁H₂₆N₄O₅S

 

A Photochromic Pyrido-Annulated 2,2-Diphenylchromene

S. Aldoshin, I. Chuev, A. Utenyshev, V. Lokshin, J. L. Pozzo, G. Pèpe and R. Guglielmetti

Formula: C₂₄H₁₇NO

 

Diethyl Methano-C₆₀-fullerene-61,61-dicarboxylate Chloroform Solvate at 193 K, C₆₀C(CO₂C₂H₅)₂.CHCl₃

E. F. Paulus and C. Bingel

Formula: C₆₇H₁₀O₄.CHCl₃

 

(-)-(S,S)--Phenyl-2-(p-tolylsulfinyl)-3-furanmethanol

R. Retoux, L. Girodier and F. Rouessac

Formula: C₁₈H₁₆O₃S

 

4a,6,7,8a-Tetrahydro[1,3]dithiolo[4',5':5,6][1,4]dithiino[2,3-b][1,4]dioxine-2-thione. A Precursor for the Preparation of New Donor Molecules and Derived Conducting Cation Radical Salts

C. Faulmann, P. Cassoux, A. I. Kotov and E. B. Yagubskii

Formula: C₇H₆O₂S₅

 

4,6,7,8,9,9a-Hexahydro-11H-pyrido[1,2-a]thieno[2,3-e][1,3]diazepin-11(10H)-one

J. Kozísek, L. Ulický, S. Marchalín, Z. Zák and B. Decroix

Formula: C₁₁H₁₄N₂OS

 

7,15,23-Triphenyl-25,26,27-triethylester-2,3,10,11,18,19-hexahomo-3,9,11-trioxacalix[3]arene in a Partial-Cone Conformation

S. Khrifi, A. Guelzim, F. Baert, M. Mussrabi, Z. Asfari and J. Vicens

Formula: C₅₄H₅₄O₁₂

 

A Revised Structure for Diethyl 5,11,17,23-Tetra-tert-butyl-26,28-bis(2-methoxyethoxy)calix[4]arene-25,27-bis(oxyacetate)

R. E. Marsh

Formula: C₅₈H₈₀O₁₀

international union of crystallography

 

Notes for Authors

Copyright © International Union of Crystallography
IUCr Webmaster