##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section C. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section C, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_lb5595
_audit_creation_method     SHELXL
_chemical_name_systematic
;
 ?
;
_chemical_name_common     ?
_chemical_formula_moiety     ?
_chemical_formula_sum     'C8 H28 B8 Cl Ir P2'
_chemical_formula_structural     ?
_chemical_formula_analytical     ?
_chemical_formula_iupac     '[Ir H (C3 H9 P)2 (C2 H8 H9 Cl)]'
_chemical_formula_weight     500.37
_chemical_melting_point     ?
_symmetry_cell_setting     Monoclinic
_symmetry_space_group_name_H-M     'P 21 /c'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x, -y-1/2, z-1/2'
_cell_length_a     9.639(2)
_cell_length_b     16.346(2)
_cell_length_c     24.1086(14)
_cell_angle_alpha     90.00
_cell_angle_beta     90.563(9)
_cell_angle_gamma     90.00
_cell_volume     3798.6(8)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     28
_cell_measurement_theta_min     5.06
_cell_measurement_theta_max     12.50
_cell_measurement_temperature     295(2)
_exptl_crystal_description     long_needle
_exptl_crystal_colour     light_yellow
_exptl_crystal_size_max     0.30
_exptl_crystal_size_mid     0.10
_exptl_crystal_size_min     0.06
_exptl_crystal_density_diffrn     1.750
_exptl_crystal_density_meas     'not measured'
_exptl_crystal_density_method     none
_exptl_crystal_F_000     1920
_exptl_absorpt_coefficient_mu     7.321
_exptl_absorpt_correction_type
                 'empirical from \y-scans  (XEMP SHELXTL-Plus; Sheldrick, 1994)'
_exptl_absorpt_correction_T_min     0.507
_exptl_absorpt_correction_T_max     0.645
_exptl_special_details
;
 ?
;
_diffrn_ambient_temperature     295(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device     'Siemens P4RA'
_diffrn_measurement_method     'ω scans'
_diffrn_reflns_number     10998
_diffrn_reflns_av_R_equivalents     0.053
_diffrn_reflns_av_sigmaI/netI     0.1275
_diffrn_reflns_theta_min     1.51
_diffrn_reflns_theta_max     27.50
_diffrn_reflns_limit_h_min     -1
_diffrn_reflns_limit_h_max     12
_diffrn_reflns_limit_k_min     -1
_diffrn_reflns_limit_k_max     21
_diffrn_reflns_limit_l_min     -31
_diffrn_reflns_limit_l_max     31
_diffrn_standards_number     3
_diffrn_standards_interval_count     97
_diffrn_standards_interval_time     ?
_diffrn_standards_decay_%     17
_refine_special_details
;
 Refinement on F² for ALL reflections except for 0 with very negative F²
 or flagged by the user for potential systematic errors.  Weighted R-factors
 wR and all goodnesses of fit S are based on F², conventional R-factors R
 are based on F, with F set to zero for negative F². The observed criterion
 of F² > 2sigma(F²) is used only for calculating _R_factor_obs etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_reflns_number_total     8733
_reflns_number_observed     5015
_reflns_observed_criterion     >2sigma(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.1329
_refine_ls_R_factor_obs     0.062
_refine_ls_wR_factor_all     0.137
_refine_ls_wR_factor_obs     0.1102
_refine_ls_goodness_of_fit_all     1.024
_refine_ls_goodness_of_fit_obs     1.112
_refine_ls_restrained_S_all     1.04
_refine_ls_restrained_S_obs     1.112
_refine_ls_number_reflns     8731
_refine_ls_number_parameters     361
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     'H-atom parameters not refined'
_refine_ls_weighting_scheme
               'calc w = 1/[\s^2^(Fo^2^)+(0.0402P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     Patterson
_atom_sites_solution_secondary     difmap
_refine_ls_shift/esd_max     -0.005
_refine_ls_shift/esd_mean     0.001
_refine_diff_density_max     1.73
_refine_diff_density_min     -0.97
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'B' 'B' 0.0013 0.0007
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'P' 'P' 0.1023 0.0942
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Ir' 'Ir' -1.4442 7.9887
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'Siemens P4RA software'
_computing_cell_refinement     'XSCANS (Siemens, 1994)'
_computing_data_reduction     'SHELXTL-Plus (Sheldrick, 1994)'
_computing_structure_solution     'SHELXTL-Plus'
_computing_structure_refinement     'SHELXTL-Plus '
_computing_molecular_graphics     'SHELXTL-Plus'
_computing_publication_material     'SHELXTL-Plus'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_thermal_displace_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_group
    Ir Ir1 0.48679(5) 0.28184(3) 0.14577(2) 0.03391(14) Uani d . 1 .
    Cl Cl 0.2767(4) 0.4165(2) 0.05377(14) 0.0575(9) Uani d . 1 .
    P P1 0.2907(4) 0.2802(2) 0.20071(14) 0.0500(9) Uani d . 1 .
    P P2 0.5993(4) 0.1691(2) 0.18216(15) 0.0498(9) Uani d . 1 .
    C C2 0.6083(12) 0.3738(7) 0.1903(5) 0.041(3) Uani d . 1 .
    B B3 0.5250(15) 0.2982(9) 0.0628(5) 0.040(3) Uani d . 1 .
    C C4 0.7363(12) 0.3702(7) 0.1552(5) 0.042(3) Uani d . 1 .
    B B5 0.4827(15) 0.4240(8) 0.1574(5) 0.040(3) Uani d . 1 .
    B B6 0.4442(15) 0.3901(9) 0.0851(5) 0.045(4) Uani d . 1 .
    B B7 0.6931(16) 0.3139(10) 0.0952(6) 0.048(4) Uani d . 1 .
    B B8 0.6581(16) 0.4644(8) 0.1598(6) 0.048(4) Uani d . 1 .
    B B9 0.6009(18) 0.3933(10) 0.0491(6) 0.056(4) Uani d . 1 .
    B B10 0.7309(19) 0.4259(10) 0.0972(6) 0.057(4) Uani d . 1 .
    B B11 0.5647(16) 0.4729(8) 0.0973(6) 0.046(4) Uani d . 1 .
    C C11 0.3141(15) 0.3143(11) 0.2719(5) 0.084(6) Uani d . 1 .
    H H11A 0.3639(15) 0.3651(11) 0.2723(5) 0.126 Uiso calc R 1 .
    H H11B 0.3658(15) 0.2739(11) 0.2923(5) 0.126 Uiso calc R 1 .
    H H11C 0.2251(15) 0.3218(11) 0.2886(5) 0.126 Uiso calc R 1 .
    C C12 0.1492(14) 0.3435(10) 0.1773(6) 0.079(5) Uani d . 1 .
    H H12A 0.1815(14) 0.3985(10) 0.1721(6) 0.118 Uiso calc R 1 .
    H H12B 0.0771(14) 0.3431(10) 0.2045(6) 0.118 Uiso calc R 1 .
    H H12C 0.1134(14) 0.3227(10) 0.1427(6) 0.118 Uiso calc R 1 .
    C C13 0.1984(17) 0.1870(11) 0.2060(8) 0.109(7) Uani d . 1 .
    H H13A 0.2602(17) 0.1446(11) 0.2184(8) 0.164 Uiso calc R 1 .
    H H13B 0.1604(17) 0.1727(11) 0.1703(8) 0.164 Uiso calc R 1 .
    H H13C 0.1245(17) 0.1932(11) 0.2321(8) 0.164 Uiso calc R 1 .
    C C21 0.6224(17) 0.0915(8) 0.1305(6) 0.088(6) Uani d . 1 .
    H H21A 0.6579(17) 0.1158(8) 0.0973(6) 0.132 Uiso calc R 1 .
    H H21B 0.5349(17) 0.0658(8) 0.1225(6) 0.132 Uiso calc R 1 .
    H H21C 0.6869(17) 0.0512(8) 0.1440(6) 0.132 Uiso calc R 1 .
    C C22 0.5327(18) 0.1092(9) 0.2394(6) 0.098(6) Uani d . 1 .
    H H22A 0.5154(18) 0.1445(9) 0.2704(6) 0.147 Uiso calc R 1 .
    H H22B 0.5997(18) 0.0684(9) 0.2499(6) 0.147 Uiso calc R 1 .
    H H22C 0.4479(18) 0.0830(9) 0.2281(6) 0.147 Uiso calc R 1 .
    C C23 0.7762(13) 0.1866(8) 0.2063(6) 0.058(4) Uani d . 1 .
    H H23A 0.7764(13) 0.2278(8) 0.2347(6) 0.086 Uiso calc R 1 .
    H H23B 0.8319(13) 0.2047(8) 0.1758(6) 0.086 Uiso calc R 1 .
    H H23C 0.8138(13) 0.1367(8) 0.2210(6) 0.086 Uiso calc R 1 .
    Ir Ir1' 1.06462(5) 0.69864(3) 0.60598(2) 0.03625(14) Uani d . 1 .
    Cl Cl' 0.9728(4) 0.4806(2) 0.6369(2) 0.0901(14) Uani d . 1 .
    P P1' 0.8672(4) 0.6959(2) 0.55031(14) 0.0507(9) Uani d . 1 .
    P P2' 1.0870(4) 0.8394(2) 0.60051(13) 0.0451(8) Uani d . 1 .
    C C2' 1.2240(13) 0.6790(8) 0.5447(5) 0.048(3) Uani d . 1 .
    B B3' 1.1260(16) 0.6362(9) 0.6776(6) 0.049(4) Uani d . 1 .
    C C4' 1.3460(13) 0.6829(7) 0.5839(5) 0.044(3) Uani d . 1 .
    B B5' 1.1442(16) 0.5908(9) 0.5528(6) 0.051(4) Uani d . 1 .
    B B6' 1.1029(15) 0.5626(10) 0.6261(7) 0.055(4) Uani d . 1 .
    B B7' 1.2870(15) 0.6787(9) 0.6523(6) 0.043(4) Uani d . 1 .
    B B8' 1.3321(18) 0.5936(10) 0.5474(7) 0.063(5) Uani d . 1 .
    B B9' 1.2611(17) 0.5646(10) 0.6645(7) 0.057(4) Uani d . 1 .
    B B10' 1.3887(16) 0.5992(9) 0.6173(7) 0.053(4) Uani d . 1 .
    B B11' 1.2610(18) 0.5268(10) 0.5948(6) 0.058(5) Uani d . 1 .
    C C11' 0.7348(13) 0.7700(8) 0.5673(5) 0.056(4) Uani d . 1 .
    H H11D 0.7744(13) 0.8239(8) 0.5674(5) 0.084 Uiso calc R 1 .
    H H11E 0.6984(13) 0.7580(8) 0.6033(5) 0.084 Uiso calc R 1 .
    H H11F 0.6614(13) 0.7674(8) 0.5402(5) 0.084 Uiso calc R 1 .
    C C12' 0.7698(14) 0.6038(9) 0.5527(6) 0.079(5) Uani d . 1 .
    H H12D 0.8290(14) 0.5583(9) 0.5443(6) 0.118 Uiso calc R 1 .
    H H12E 0.6954(14) 0.6063(9) 0.5260(6) 0.118 Uiso calc R 1 .
    H H12F 0.7323(14) 0.5969(9) 0.5892(6) 0.118 Uiso calc R 1 .
    C C13' 0.8946(15) 0.7100(8) 0.4764(5) 0.063(4) Uani d . 1 .
    H H13D 0.9468(15) 0.7592(8) 0.4704(5) 0.095 Uiso calc R 1 .
    H H13E 0.8065(15) 0.7142(8) 0.4576(5) 0.095 Uiso calc R 1 .
    H H13F 0.9449(15) 0.6641(8) 0.4620(5) 0.095 Uiso calc R 1 .
    C C21' 1.2608(15) 0.8751(8) 0.6158(6) 0.078(5) Uani d . 1 .
    H H21D 1.2930(15) 0.8510(8) 0.6499(6) 0.117 Uiso calc R 1 .
    H H21E 1.2603(15) 0.9336(8) 0.6194(6) 0.117 Uiso calc R 1 .
    H H21F 1.3215(15) 0.8596(8) 0.5863(6) 0.117 Uiso calc R 1 .
    C C22' 1.0500(14) 0.8927(8) 0.5357(5) 0.059(4) Uani d . 1 .
    H H22D 0.9583(14) 0.8788(8) 0.5229(5) 0.089 Uiso calc R 1 .
    H H22E 1.1163(14) 0.8766(8) 0.5083(5) 0.089 Uiso calc R 1 .
    H H22F 1.0558(14) 0.9507(8) 0.5416(5) 0.089 Uiso calc R 1 .
    C C23' 0.9853(17) 0.8986(10) 0.6510(6) 0.092(6) Uani d . 1 .
    H H23D 0.8888(17) 0.8850(10) 0.6470(6) 0.139 Uiso calc R 1 .
    H H23E 0.9979(17) 0.9560(10) 0.6443(6) 0.139 Uiso calc R 1 .
    H H23F 1.0163(17) 0.8856(10) 0.6879(6) 0.139 Uiso calc R 1 .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ir1 B3 . 2.054(12) ?
    Ir1 C2 . 2.183(11) ?
    Ir1 P2 . 2.308(3) ?
    Ir1 P1 . 2.319(3) ?
    Ir1 B6 . 2.330(14) ?
    Ir1 B5 . 2.341(14) ?
    Ir1 B7 . 2.40(2) ?
    Cl B6 . 1.827(15) ?
    P1 C13 . 1.770(15) ?
    P1 C12 . 1.798(14) ?
    P1 C11 . 1.816(13) ?
    P2 C21 . 1.793(13) ?
    P2 C22 . 1.813(14) ?
    P2 C23 . 1.820(13) ?
    C2 C4 . 1.50(2) ?
    C2 B5 . 1.66(2) ?
    C2 B8 . 1.72(2) ?
    B3 B9 . 1.75(2) ?
    B3 B6 . 1.78(2) ?
    B3 B7 . 1.81(2) ?
    C4 B10 . 1.67(2) ?
    C4 B8 . 1.72(2) ?
    C4 B7 . 1.76(2) ?
    B5 B8 . 1.82(2) ?
    B5 B11 . 1.84(2) ?
    B5 B6 . 1.86(2) ?
    B6 B9 . 1.75(2) ?
    B6 B11 . 1.81(2) ?
    B7 B10 . 1.87(2) ?
    B7 B9 . 1.92(2) ?
    B8 B11 . 1.75(2) ?
    B8 B10 . 1.78(2) ?
    B9 B10 . 1.78(2) ?
    B9 B11 . 1.78(2) ?
    B10 B11 . 1.78(2) ?
    Ir1' B3' . 2.086(14) ?
    Ir1' C2' . 2.165(12) ?
    Ir1' B6' . 2.31(2) ?
    Ir1' B5' . 2.315(15) ?
    Ir1' P2' . 2.316(3) ?
    Ir1' P1' . 2.318(3) ?
    Ir1' B7' . 2.429(14) ?
    Cl' B6' . 1.856(15) ?
    P1' C12' . 1.776(14) ?
    P1' C11' . 1.809(13) ?
    P1' C13' . 1.819(11) ?
    P2' C21' . 1.809(13) ?
    P2' C22' . 1.822(11) ?
    P2' C23' . 1.844(14) ?
    C2' C4' . 1.50(2) ?
    C2' B5' . 1.65(2) ?
    C2' B8' . 1.74(2) ?
    B3' B6' . 1.74(2) ?
    B3' B9' . 1.78(2) ?
    B3' B7' . 1.81(2) ?
    C4' B10' . 1.64(2) ?
    C4' B8' . 1.71(2) ?
    C4' B7' . 1.75(2) ?
    B5' B8' . 1.82(2) ?
    B5' B11' . 1.83(2) ?
    B5' B6' . 1.87(2) ?
    B6' B9' . 1.78(2) ?
    B6' B11' . 1.81(2) ?
    B7' B10' . 1.84(2) ?
    B7' B9' . 1.91(2) ?
    B8' B11' . 1.73(2) ?
    B8' B10' . 1.77(2) ?
    B9' B10' . 1.78(2) ?
    B9' B11' . 1.79(2) ?
    B10' B11' . 1.79(2) ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    B3 Ir1 C2 . . 106.8(5) ?
    B3 Ir1 P2 . . 112.7(4) ?
    C2 Ir1 P2 . . 96.6(3) ?
    B3 Ir1 P1 . . 135.4(4) ?
    C2 Ir1 P1 . . 99.4(3) ?
    P2 Ir1 P1 . . 99.00(13) ?
    B3 Ir1 B6 . . 47.3(5) ?
    C2 Ir1 B6 . . 82.9(5) ?
    P2 Ir1 B6 . . 157.6(4) ?
    P1 Ir1 B6 . . 103.2(4) ?
    B3 Ir1 B5 . . 89.4(5) ?
    C2 Ir1 B5 . . 42.8(5) ?
    P2 Ir1 B5 . . 139.1(4) ?
    P1 Ir1 B5 . . 85.9(3) ?
    B6 Ir1 B5 . . 47.0(5) ?
    B3 Ir1 B7 . . 47.1(5) ?
    C2 Ir1 B7 . . 69.9(5) ?
    P2 Ir1 B7 . . 88.8(4) ?
    P1 Ir1 B7 . . 167.6(4) ?
    B6 Ir1 B7 . . 69.9(5) ?
    B5 Ir1 B7 . . 81.9(5) ?
    C13 P1 C12 . . 97.9(8) ?
    C13 P1 C11 . . 104.7(8) ?
    C12 P1 C11 . . 102.0(8) ?
    C13 P1 Ir1 . . 117.6(6) ?
    C12 P1 Ir1 . . 115.7(5) ?
    C11 P1 Ir1 . . 116.2(5) ?
    C21 P2 C22 . . 101.2(8) ?
    C21 P2 C23 . . 102.2(7) ?
    C22 P2 C23 . . 100.4(7) ?
    C21 P2 Ir1 . . 111.2(5) ?
    C22 P2 Ir1 . . 123.5(6) ?
    C23 P2 Ir1 . . 115.5(4) ?
    C4 C2 B5 . . 110.4(10) ?
    C4 C2 B8 . . 63.9(8) ?
    B5 C2 B8 . . 64.9(8) ?
    C4 C2 Ir1 . . 97.7(7) ?
    B5 C2 Ir1 . . 73.7(6) ?
    B8 C2 Ir1 . . 122.1(8) ?
    B9 B3 B6 . . 59.5(8) ?
    B9 B3 B7 . . 65.3(9) ?
    B6 B3 B7 . . 98.3(10) ?
    B9 B3 Ir1 . . 112.2(8) ?
    B6 B3 Ir1 . . 74.5(6) ?
    B7 B3 Ir1 . . 76.5(6) ?
    C2 C4 B10 . . 115.6(11) ?
    C2 C4 B8 . . 64.3(8) ?
    B10 C4 B8 . . 63.6(9) ?
    C2 C4 B7 . . 107.1(9) ?
    B10 C4 B7 . . 65.9(8) ?
    B8 C4 B7 . . 114.9(10) ?
    C2 B5 B8 . . 59.3(8) ?
    C2 B5 B11 . . 105.9(10) ?
    B8 B5 B11 . . 57.3(8) ?
    C2 B5 B6 . . 116.1(10) ?
    B8 B5 B6 . . 108.4(9) ?
    B11 B5 B6 . . 58.4(7) ?
    C2 B5 Ir1 . . 63.5(6) ?
    B8 B5 Ir1 . . 110.4(8) ?
    B11 B5 Ir1 . . 109.2(8) ?
    B6 B5 Ir1 . . 66.2(6) ?
    B9 B6 B3 . . 59.5(8) ?
    B9 B6 B11 . . 60.1(8) ?
    B3 B6 B11 . . 113.5(10) ?
    B9 B6 Cl . . 123.5(9) ?
    B3 B6 Cl . . 117.6(9) ?
    B11 B6 Cl . . 117.0(9) ?
    B9 B6 B5 . . 106.8(10) ?
    B3 B6 B5 . . 116.8(10) ?
    B11 B6 B5 . . 60.2(8) ?
    Cl B6 B5 . . 118.9(9) ?
    B9 B6 Ir1 . . 100.7(9) ?
    B3 B6 Ir1 . . 58.2(6) ?
    B11 B6 Ir1 . . 111.0(8) ?
    Cl B6 Ir1 . . 126.1(7) ?
    B5 B6 Ir1 . . 66.8(6) ?
    C4 B7 B3 . . 129.2(10) ?
    C4 B7 B10 . . 54.7(7) ?
    B3 B7 B10 . . 108.9(11) ?
    C4 B7 B9 . . 103.0(10) ?
    B3 B7 B9 . . 55.9(8) ?
    B10 B7 B9 . . 56.0(8) ?
    C4 B7 Ir1 . . 83.5(7) ?
    B3 B7 Ir1 . . 56.3(6) ?
    B10 B7 Ir1 . . 111.3(9) ?
    B9 B7 Ir1 . . 93.4(8) ?
    C4 B8 C2 . . 51.9(7) ?
    C4 B8 B11 . . 103.7(9) ?
    C2 B8 B11 . . 107.0(10) ?
    C4 B8 B10 . . 56.9(8) ?
    C2 B8 B10 . . 99.9(9) ?
    B11 B8 B10 . . 60.3(9) ?
    C4 B8 B5 . . 94.7(9) ?
    C2 B8 B5 . . 55.8(7) ?
    B11 B8 B5 . . 62.0(8) ?
    B10 B8 B5 . . 102.6(10) ?
    B6 B9 B3 . . 61.0(9) ?
    B6 B9 B10 . . 107.0(10) ?
    B3 B9 B10 . . 115.9(11) ?
    B6 B9 B11 . . 61.5(8) ?
    B3 B9 B11 . . 116.2(11) ?
    B10 B9 B11 . . 59.8(9) ?
    B6 B9 B7 . . 95.2(10) ?
    B3 B9 B7 . . 58.8(8) ?
    B10 B9 B7 . . 60.5(9) ?
    B11 B9 B7 . . 102.1(10) ?
    C4 B10 B11 . . 104.8(11) ?
    C4 B10 B9 . . 113.4(11) ?
    B11 B10 B9 . . 60.1(9) ?
    C4 B10 B8 . . 59.5(8) ?
    B11 B10 B8 . . 59.0(9) ?
    B9 B10 B8 . . 112.1(12) ?
    C4 B10 B7 . . 59.4(8) ?
    B11 B10 B7 . . 104.4(11) ?
    B9 B10 B7 . . 63.5(9) ?
    B8 B10 B7 . . 106.8(10) ?
    B8 B11 B10 . . 60.8(9) ?
    B8 B11 B9 . . 113.6(11) ?
    B10 B11 B9 . . 60.1(9) ?
    B8 B11 B6 . . 113.9(10) ?
    B10 B11 B6 . . 104.8(10) ?
    B9 B11 B6 . . 58.4(8) ?
    B8 B11 B5 . . 60.7(8) ?
    B10 B11 B5 . . 102.0(10) ?
    B9 B11 B5 . . 106.5(10) ?
    B6 B11 B5 . . 61.4(8) ?
    B3' Ir1' C2' . . 107.1(6) ?
    B3' Ir1' B6' . . 46.4(6) ?
    C2' Ir1' B6' . . 83.5(5) ?
    B3' Ir1' B5' . . 89.6(6) ?
    C2' Ir1' B5' . . 43.0(5) ?
    B6' Ir1' B5' . . 47.8(6) ?
    B3' Ir1' P2' . . 120.5(4) ?
    C2' Ir1' P2' . . 92.4(3) ?
    B6' Ir1' P2' . . 163.0(4) ?
    B5' Ir1' P2' . . 133.9(4) ?
    B3' Ir1' P1' . . 134.0(4) ?
    C2' Ir1' P1' . . 100.7(4) ?
    B6' Ir1' P1' . . 103.4(4) ?
    B5' Ir1' P1' . . 86.5(4) ?
    P2' Ir1' P1' . . 93.59(12) ?
    B3' Ir1' B7' . . 46.5(5) ?
    C2' Ir1' B7' . . 70.4(5) ?
    B6' Ir1' B7' . . 68.6(5) ?
    B5' Ir1' B7' . . 81.8(5) ?
    P2' Ir1' B7' . . 94.4(4) ?
    P1' Ir1' B7' . . 168.3(4) ?
    C12' P1' C11' . . 100.7(7) ?
    C12' P1' C13' . . 102.8(7) ?
    C11' P1' C13' . . 104.3(6) ?
    C12' P1' Ir1' . . 115.4(5) ?
    C11' P1' Ir1' . . 115.7(5) ?
    C13' P1' Ir1' . . 116.0(5) ?
    C21' P2' C22' . . 101.2(6) ?
    C21' P2' C23' . . 101.2(8) ?
    C22' P2' C23' . . 102.4(7) ?
    C21' P2' Ir1' . . 113.3(5) ?
    C22' P2' Ir1' . . 120.4(5) ?
    C23' P2' Ir1' . . 115.7(6) ?
    C4' C2' B5' . . 109.0(11) ?
    C4' C2' B8' . . 63.0(9) ?
    B5' C2' B8' . . 64.8(9) ?
    C4' C2' Ir1' . . 96.9(8) ?
    B5' C2' Ir1' . . 73.4(7) ?
    B8' C2' Ir1' . . 121.4(9) ?
    B6' B3' B9' . . 60.5(9) ?
    B6' B3' B7' . . 97.4(11) ?
    B9' B3' B7' . . 64.1(9) ?
    B6' B3' Ir1' . . 73.4(7) ?
    B9' B3' Ir1' . . 112.1(10) ?
    B7' B3' Ir1' . . 76.7(7) ?
    C2' C4' B10' . . 117.7(11) ?
    C2' C4' B8' . . 65.4(9) ?
    B10' C4' B8' . . 63.8(9) ?
    C2' C4' B7' . . 109.3(10) ?
    B10' C4' B7' . . 65.6(8) ?
    B8' C4' B7' . . 115.3(10) ?
    C2' B5' B8' . . 60.1(9) ?
    C2' B5' B11' . . 106.2(11) ?
    B8' B5' B11' . . 56.4(9) ?
    C2' B5' B6' . . 115.5(11) ?
    B8' B5' B6' . . 107.2(11) ?
    B11' B5' B6' . . 58.3(8) ?
    C2' B5' Ir1' . . 63.7(6) ?
    B8' B5' Ir1' . . 110.9(9) ?
    B11' B5' Ir1' . . 109.5(9) ?
    B6' B5' Ir1' . . 65.8(7) ?
    B3' B6' B9' . . 60.8(9) ?
    B3' B6' B11' . . 114.8(11) ?
    B9' B6' B11' . . 60.0(9) ?
    B3' B6' Cl' . . 118.8(11) ?
    B9' B6' Cl' . . 121.2(10) ?
    B11' B6' Cl' . . 113.5(11) ?
    B3' B6' B5' . . 118.4(11) ?
    B9' B6' B5' . . 107.3(11) ?
    B11' B6' B5' . . 59.7(8) ?
    Cl' B6' B5' . . 117.4(10) ?
    B3' B6' Ir1' . . 60.2(7) ?
    B9' B6' Ir1' . . 103.1(9) ?
    B11' B6' Ir1' . . 111.0(9) ?
    Cl' B6' Ir1' . . 128.3(8) ?
    B5' B6' Ir1' . . 66.4(6) ?
    C4' B7' B3' . . 128.3(11) ?
    C4' B7' B10' . . 54.3(8) ?
    B3' B7' B10' . . 110.2(10) ?
    C4' B7' B9' . . 103.2(10) ?
    B3' B7' B9' . . 57.2(8) ?
    B10' B7' B9' . . 56.6(8) ?
    C4' B7' Ir1' . . 81.7(7) ?
    B3' B7' Ir1' . . 56.7(6) ?
    B10' B7' Ir1' . . 110.9(8) ?
    B9' B7' Ir1' . . 94.9(8) ?
    C4' B8' B11' . . 103.2(11) ?
    C4' B8' C2' . . 51.6(7) ?
    B11' B8' C2' . . 106.9(11) ?
    C4' B8' B10' . . 56.2(8) ?
    B11' B8' B10' . . 61.5(10) ?
    C2' B8' B10' . . 100.0(10) ?
    C4' B8' B5' . . 93.3(10) ?
    B11' B8' B5' . . 62.2(9) ?
    C2' B8' B5' . . 55.1(8) ?
    B10' B8' B5' . . 103.4(12) ?
    B3' B9' B6' . . 58.6(9) ?
    B3' B9' B10' . . 114.6(12) ?
    B6' B9' B10' . . 105.6(11) ?
    B3' B9' B11' . . 113.5(11) ?
    B6' B9' B11' . . 60.8(9) ?
    B10' B9' B11' . . 60.2(9) ?
    B3' B9' B7' . . 58.7(8) ?
    B6' B9' B7' . . 92.9(10) ?
    B10' B9' B7' . . 59.8(8) ?
    B11' B9' B7' . . 101.0(11) ?
    C4' B10' B8' . . 60.1(9) ?
    C4' B10' B9' . . 114.1(11) ?
    B8' B10' B9' . . 112.6(11) ?
    C4' B10' B11' . . 103.5(10) ?
    B8' B10' B11' . . 58.1(9) ?
    B9' B10' B11' . . 60.3(9) ?
    C4' B10' B7' . . 60.1(8) ?
    B8' B10' B7' . . 108.2(10) ?
    B9' B10' B7' . . 63.6(9) ?
    B11' B10' B7' . . 103.8(10) ?
    B8' B11' B10' . . 60.4(10) ?
    B8' B11' B9' . . 114.0(13) ?
    B10' B11' B9' . . 59.5(9) ?
    B8' B11' B6' . . 114.5(11) ?
    B10' B11' B6' . . 103.9(11) ?
    B9' B11' B6' . . 59.2(9) ?
    B8' B11' B5' . . 61.3(9) ?
    B10' B11' B5' . . 102.0(11) ?
    B9' B11' B5' . . 108.4(11) ?
    B6' B11' B5' . . 61.9(9) ?
data_global
_journal_date_recd_electronic     1996-02-12
_journal_date_accepted     1996-11-13
_journal_name_full     'Acta Crystallographica, Section C'
_journal_year     1997
_journal_volume     53
_journal_issue     4
_journal_page_first     416
_journal_page_last     419
_journal_paper_category     FM
_journal_coeditor_code     BK1240
_publ_contact_author
;
Dr Nigam P. Rath
Department of Chemistry
University of Missouri--St. Louis
8001 Natural Bridge Road
St. Louis
MO 63121
USA
;
_publ_contact_author_email     'Nigam_Rath@umsl.edu'
_publ_contact_author_fax     '314 516 5342'
_publ_contact_author_phone     '314 516 5333'
_publ_section_title
;
The isonido-Metalladicarbaborane
[1,1,1-H{P(CH₃)₃}₂-6-Cl-1,2,4-IrC₂B₈H₉]
;
loop_
    _publ_author_name
    _publ_author_address
    'Bould, Jonathan'
;     Department of Chemistry
      University of Missouri -- St. Louis
      8001 Natural Bridge Road
      St. Louis, MO 63121
      USA
;
    'Rath, Nigam P.'
;     Department of Chemistry
      University of Missouri -- St. Louis
      8001 Natural Bridge Road
      St. Louis, MO 63121
      USA
;
    'Barton, Lawrence'
;     Department of Chemistry
      University of Missouri -- St. Louis
      8001 Natural Bridge Road
      St. Louis, MO 63121
      USA
;
