Acta Crystallographica Section C

Crystal Structure Communications

Volume 53, Part 10 (October 1997)

Cover illustration: 1:1 Molecular Complex Between Water and a Macrocyclic Crown Phosphonamide, see Declercq, Delangle, Dutasta, Van Oostenryck and Tinant, pages 1484-1486. Displacement ellipsoids are shown at the 50% probability level for non-H atoms.

• cif-access (metal-organic compounds)
• cif-access (organic compounds)
• inorganic compounds
• metal-organic compounds
• organic compounds

cif-access (metal-organic compounds)

 

Bis[2-(dimethylamino)pyridinium] Tetrachlorocobaltate(II)

J. M. Land, R. G. Baughman and C. A. Hester

Formula: (C₇H₁₁N₂)₂[CoCl₄]

cif-access (organic compounds)

 

Dimedone at 133K

M. Bolte and M. Scholtyssik

Formula: C₈H₁₂O₂

 

4-Ethyl-2-[4-hydroxy-5-(1-hydroxypropyl)-2-phenyl-2-cyclohexenyl]-3-tosyl-1,3-oxazolidine

M. Bolte and S. Monz

Formula: C₂₇H₃₅NO₅S

 

1,3-Bis(2,4,6-triphenylpyrimidin-5-yl)urea-Acetone (1/1) at 133K

M. Bolte

Formula: C₄₅H₃₂N₆O.C₃H₆O

 

Conformation of (S,S)-Methyl (2-Methyl-4-phenylbutanamido)(phenyl)acetate

Y. Inouye, T. Yabuuti and T. Kusumi

Formula: C₂₀H₂₃NO₃

 

Hydrogen Bond Network in Ethylenediammonium Bis(hydrogenmaleate)

J. C. Barnes and T. J. R. Weakley

Formula: C₂H₁₀N₂²⁺.2C₄H₃O₄^-

inorganic compounds

 

Ca₃Y₂(SiO₄)₃

H. Yamane, T. Nagasawa, M. Shimada and T. Endo

Synopsis: Ca₃Y₂(SiO₄)₃ is isostructural with silico-carnotite, Ca₅(PO₄)₂SiO₄. The structure contains isolated SiO₄ tetrahedra. The three large cation sites are occupied by both Ca and Y in specific ratios.

Formula: Ca₃Y₂(SiO₄)₃

 

Brochantite

M. Helliwell and J. V. Smith

Synopsis: A new determination of the structure of brochantite using a single crystal shows that pairs of Cu atoms are bonded to form almost linear chains bridged by O atoms. The Cu atoms have distorted octahedral coordination to hydroxyl or sulfate O atoms.

Formula: Cu₄SO₄(OH)₆

 

A Reinvestigation of Cu₃Mo₂O₉, a Compound Containing Copper(II) in Compressed Octahedral Coordination

U. Steiner and W. Reichelt

Synopsis: The structure of Cu₃Mo₂O₉ consists of strings of corner-sharing CuO₆ octahedra linked to CuO₅ square pyramids and MoO₄ tetrahedra by edges and corners, respectively. The structure contains the Jahn-Teller active ion Cu²⁺ in unusual compressed octahedral coordination.

Formula: Cu₃Mo₂O₉

metal-organic compounds

 

The Layered Methylammonium Molybdate (NH₃CH₃)₂[Mo₇O₂₂] from X-ray Powder Data

P. Y. Zavalij and M. S. Whittingham

Synopsis: Rietveld refinement of a new layered molybdate from the [Mo_nO_3n+1]^2- series, (NH₃CH₃)₂[Mo₇O₂₂], showed that the molybdenum coordination polyhedra are significantly distorted octahedra. The methylammonium cations are incorporated between the layers.

Formula: (NH₃CH₃)₂[Mo₇O₂₂]

 

Potassium Diaqua(ethylenediaminetetraacetato)ytterbate(III) Pentahydrate

N. Sakagami, J.-I. Homma, T. Konno and K.-I. Okamoto

Formula: K[Yb(C₁₀H₁₂N₂O₈)(H₂O)₂].5H₂O

 

Tetracaesium Bis(diethylenetriamine-N,N,N',N'',N''-pentacetato)didysprosate(III) Tridecahydrate

N. Sakagami, J.-I. Homma, T. Konno and K.-I. Okamoto

Formula: Cs₄[Dy₂(C₁₄H₁₈N₃O₁₀)₂].13H₂O

 

Tetrakis(ethylenediamine)yttrium(III) Hydrosulfide Iodide

C. George and A. P. Purdy

Formula: [Y(C₂H₈N₂)₄](SH)_2.72I_0.28

 

(2S)-(+)-Dicarbonyl(⁴-2,6,6-trimethylcyclohepta-2,4-dienone)(triphenylphosphine-P)iron

T. Petrowitsch, R. Grosser, M. Schürmann, H. Preut and P. Eilbracht

Formula: [Fe(C₁₀H₁₄O)(C₁₈H₁₅P)(CO)₂]

 

A cis-Octahedral Dichloro Complex of Fe^III with a Tetradentate Dipyridyl-Diamino Ligand

N. W. Alcock, E. V. Rybak-Akimova and D. H. Busch

Formula: [FeCl₂(C₁₅H₂₀N₄)]ClO₄

 

catena-Poly[[(1,4-dioxane-O¹)iodolithium]--(1,4-dioxane-O¹:O⁴)]

C. Eaborn, A. Farook, P. B. Hitchcock and J. D. Smith

Formula: [LiI(C₄H₈O₂)₂]

 

Aquatetrachlorotris(tetrahydrofuran-O)thorium(IV) Tetrahydrofuran Solvate (1/1)

M. P. Spry, W. Errington and G. R. Willey

Formula: [ThCl₄(C₄H₈O)₃(H₂O)].C₄H₈O

 

trans-Tribromotris(1,3-thiazole-N)molybdenum(III)

M. James, H. Kawaguchi and K. Tatsumi

Formula: [MoBr₃(C₃H₃NS)₃]

 

[(Mg_0.5,Mn_0.5)₄{₃,²-OCH₂CH(CH₂)₃O}₄(EtOH)₄Cl₄].0.5EtOH

L. B. Jerzykiewicz, J. Utko and P. Sobota

Formula: [(Mg_0.5,Mn_0.5)₄Cl₄(C₂H₆O)₄(C₅H₉O₂)₄].0.5C₂H₆O

 

Silver Acetate-Triphenylphosphine Complexes. Acetatobis(triphenylphosphine)silver(I) and its Sesquihydrate, and Bis[acetato(triphenylphosphine)silver(I)] Hydrate and its Hemihydrate

S. W. Ng and A. H. Othman

Formula: [Ag(C₂H₃O₂)(C₁₈H₁₅P)₂], [Ag(C₂H₃O₂)(C₁₈H₁₅P)₂].1.5H₂O, [Ag₂(C₂H₃O₂)₂(C₁₈H₁₅P)₂].H₂O and [Ag₂(C₂H₃O₂)₂(C₁₈H₁₅P)₂].0.5H₂O

 

Chlorobis[1,1'-diphenylhydrazido(2-)-N²][hydridotris(pyrazolyl-N²)borato]molybdenum(VI)

C. Manzur, D. Carrillo and D. Boys

Formula: [MoCl(C₉H₁₀BN₆)(C₁₂H₁₀N₂)₂]

 

Carbonyl(1,3-diphenyl-1,3-propanedionato-O,O')(triphenylphosphine-P)rhodium(I)

D. Lamprecht, G. J. Lamprecht, J. M. Botha, K. Umakoshi and Y. Sasaki

Formula: [Rh(C₁₅H₁₁O₂)(C₁₈H₁₅P)(CO)]

 

trans-[Bis-2,6-(2-benzimidazolyl-N²)pyridine-N]nitrobis(triphenylphosphine-P)ruthenium(II) Perchlorate Ethanol Solvate

J. W. Lim, H. J. Yeo and J. H. Jeong

Formula: [Ru(NO₂)(C₁₉H₁₃N₅)(C₁₈H₁₅P)₂]ClO₄.C₂H₆O

 

Bis(piperidinium) Tetrachloromercurate

R. Spengler, F. Zouari, A. Ben Salah and H. Burzlaff

Formula: (C₅H₁₂N)₂[HgCl₄]

 

Monodentate Ligation of Tetracyanonickelate(II): (2-Aminoethanol)[N-(2-aminoethyl)-1,2-ethanediamine][tetracyanonickelato(II)]copper(II)-Water (1/2)

H. Kurihara, S.-I. Nishikiori and T. Iwamoto

Formula: [CuNi(CN)₄(C₄H₁₃N₃)(C₂H₇NO)].2H₂O

 

trans-[2,6-Diacetylpyridine bis(thiosemicarbazone)(1-)]diphenyltin(IV) Chloride

P. C. Moreno, R. H. P. Francisco, M. T. doP. Gambardella, G. F. de Sousa and A. Abras

Formula: [Sn(C₆H₅)₂(C₁₁H₁₄N₇S₂)]Cl

 

trans-Dichlorobis(ferrocenyldiphenylphosphine-P)platinum(II)-Benzene (1/2)

S. Otto and A. Roodt

Formula: [PtCl₂(C₂₂H₁₉FeP)₂].2C₆H₆

 

endo and exo Isomers of Isodicyclopentadienyltrichlorotitanium

J. C. Gallucci, N. Kozmina, L. A. Paquette, F. Zaegel, P. Meunier and B. Gautheron

Formula: Two isomers of [TiCl₃(C₁₀H₁₁)]

 

Bis(nicotinamide-N)bis(salicylato-O,O')copper(II), the Monoclinic Form

I. Leban, B. Kozlevcar, J. Sieler and P. Segedin

Formula: [Cu(C₇H₅O₃)₂(C₆H₆N₂O)₂]

 

Diaquabis(dimethyl 3-oxopentanedioato-O¹,O³)zinc(II)

J. Fawcett, R. D. W. Kemmitt, D. R. Russell and K. Singh

Formula: [Zn(C₇H₉O₅)₂(H₂O)₂]

organic compounds

 

1,4-Dimethoxy-2-naphthoic Acid

A. C. Blackburn and R. E. Gerkin

Formula: C₁₃H₁₂O₄

 

2-Aminonicotinic Acid

A. J. Dobson and R. E. Gerkin

Formula: C₆H₆N₂O₂

 

Polysulfonylamines. LXXXVII. Bis(benzenesulfonamido) Sulfone-Dichloromethane (1/0.5)

O. Hiemisch, D. Henschel, A. Blaschette and P. G. Jones

Formula: C₁₂H₁₂N₂O₆S₃.0.5CH₂Cl₂

 

5-Iodo-2-[iodo(5-iodo-1,3,3-trimethyl-2-indolinylidene)methyl]-1,3,3-trimethyl-3H-indolium Perchlorate: a Highly Overcrowded Cyanine Dye

H.-H. Johannes, W. Grahn, I. Dix and P. G. Jones

Formula: C₂₃H₂₄I₃N₂⁺.ClO₄^-

 

1-Acetamidoadamantane

H.-H. Pröhl, A. Blaschette and P. G. Jones

Formula: C₁₂H₁₉NO

 

3-Cyano-6-(4-methoxyphenyl)-5-methyl-4-methylthio-2H-pyran-2-one

A. Azim, V. S. Parmar and W. Errington

Formula: C₁₅H₁₃NO₃S

 

1-(3,4-Dimethoxyphenyl)-3-(3-methylphenyl)prop-2-en-1-one

N. K. Sharma, R. Kumar, V. S. Parmar and W. Errington

Formula: C₁₈H₁₈O₃

 

1-(2-Acetoxy-4-methoxyphenyl)-2-phenylethanone

H. N. Pati, V. S. Parmar and W. Errington

Formula: C₁₇H₁₆O₄

 

3-Cyano-6-(2-methoxyphenyl)-4-methylthio-2H-pyran-2-one

S. Malhotra, V. S. Parmar and W. Errington

Formula: C₁₄H₁₁NO₃S

 

The Novel Fragrance 2-Isobutyl-4-oxo-5,5-dimethyltetrahydropyran as its 2,4-Dinitrophenylhydrazone Derivative

A. L. Lane, K. J. Rossiter, C. S. Sell and D. J. Watkin

Formula: C₁₇H₂₄N₄O₅

 

A trans-1,2-Diarylhexafluorocyclobutane

D. C. Swenson, M. Yamamoto and D. J. Burton

Formula: C₄₄H₂₄F₆N₂O₆.C₄H₁₀O

 

Tubingensin B, a Cytotoxic Carbazole Alkaloid from the Sclerotia of Aspergillus tubingensis

D. C. Swenson, M. R. TePaske, N. C. Baenziger and J. B. Gloer

Formula: C₂₈H₃₅NO.0.5CHCl₃

 

Phenylpyruvic Acid

N. Okabe and C. Inubushi

Formula: C₉H₈O₃

 

Tris(3-chlorophenyl)phosphine Oxide

O. bin Shawkataly, K. Ramalingam, S. Selvakumar, H.-K. Fun and A. R. Ibrahim

Formula: C₁₈H₁₂Cl₃OP

 

p-Nitrobenzaldehyde Isonicotinoylhydrazone

H.-K. Fun, Z.-L. Lu, C.-Y. Duan, Y.-P. Tian, X.-Z. You, Y.-M. Guo and X.-Y. Gong

Formula: C₁₃H₁₀N₄O₃

 

p-(Dimethylamino)benzaldehyde Benzoylhydrazone Monohydrate

H.-K. Fun, Z.-L. Lu, C.-Y. Duan, Y.-P. Tian, X.-Z. You, X.-Y. Gong and Y.-M. Guo

Formula: C₁₆H₁₇N₃O.H₂O

 

The Chelating Agent N,N,N',N'',N''',N'''-Triethylenetetraminehexacetic Acid (TTHA)

D. C. Finnen and A. A. Pinkerton

Formula: C₁₈H₃₀N₄O₁₂

 

An Enantiomerically Pure Schiff Base Ligand

A. S. Abu-Surrah, T. V. Laine, T. Repo, R. Fawzi, M. Steimann and B. Rieger

Formula: C₂₆H₂₄N₄

 

2,4,6,8-Tetraazabicyclo[3.3.1]nonane-3,7-dione and 2,4,6,8-Tetraacetyl-2,4,6,8-tetraazabicyclo[3.3.1]nonane-3,7-dione

G. Piacenza, C. Beguet, E. Wimmer, R. Gallo and M. Giorgi

Formula: C₅H₈N₄O₂ and C₁₃H₁₆N₄O₆

 

Dimethyl 2-Iodobenzoylphosphonate, an Unusual Example of a Crystalline -Ketophosphonate

D. V. Griffiths, J. E. Harris and J. R. Miller

Formula: C₉H₁₀IO₄P

 

2-(3-Nitrophenyl)-1,3-dioxolane at 150K

M. Bolte, R. Marx and M. Scholtyssik

Formula: C₉H₉NO₄

 

(1R,2S,4S,11S)-4-Isopropyl-1-methyl-2-(-N-morpholino-3-methoxybenzyl)cyclohexan-3-one

M. Ertan, A. Yesilada, B. Tozkoparan, Ç Tarimci, B. Krebs and M. Läge

Formula: C₂₂H₃₃NO₃

 

Three trans-2,6-Diaryl Derivatives of Oximes of N-Hydroxy-4-piperidone

E. Díaz, H. Barrios and R. A. Toscano

Formula: C₁₇H₁₈N₂O₂, C₁₅H₂₀N₄O₂ and C₁₃H₁₄N₂O₂S₂

 

9a-Trimethylsilyloctahydroquinolizinium Picrate

J. M. White and W.-Y. Tham

Formula: C₁₂H₂₆NSi⁺.C₆H₂N₃O₇^-

 

A Putrescine Triamide from Lilium regale

A. Linden, P. Kuehne and M. Hesse

Formula: C₁₈H₂₂N₂O₄

 

Photoproducts Derived from 9-Substituted Dibenzobarrelenes

M. Muneer, N. P. Rath and M. V. George

Formula: Two isomers of C₃₁H₂₂O₃

 

Tyrosinium-D-tetrahydroisoquinoline-3-carboxylate 1.5-Hydrate and Tyrosyl-D-tetrahydroisoquinoline-3-carboxamide Hydrate

J. R. Deschamps, J. L. Flippen-Anderson, C. Moore, R. Cudney and C. George

Formula: C₁₉H₂₀N₂O₄.1.5H₂O and C₁₉H₂₁N₃O₃.H₂O

 

Intermediates in the Synthesis of Daphniphyllum Alkaloids. I. A Tetracyclic Oxygen Analogue

J. Zukerman-Schpector, E. E. Castellano, M. A. Ceschi, T. J. Brocksom and J. L. Wikaira

Formula: C₂₀H₂₅BrO₄

 

1:1 Molecular Complex Between Water and a Macrocyclic Crown Phosphonamide

J.-P. Declercq, P. Delangle, J.-P. Dutasta, L. Van Oostenryck and B. Tinant

Formula: C₂₁H₂₉N₂O₄PS.H₂O

 

Out-of-Plane Orientation of the Carbamoyl Group in an NAD Model Compound: Preferred 1,3-Diaxial Methyl Configuration

Y. Mikata

Formula: C₁₄H₂₁N₂O⁺.I^-

 

A Nitroxide Tetraradical Exhibiting Ferromagnetic Coupling

K. Griesar, W. Haase, I. Svoboda and H. Fuess

Formula: C₄₆H₇₀N₄O₁₂

 

Unique trans-syn-cis [6.6.7] Tricycle Derivative from Transannular Diels-Alder Contraction of a Model 15-Membered trans-cis-cis Macrocyclic Triene

M. Drouin, D. G. Hall, A.-S. Caillé and P. Deslongchamps

Formula: C₂₄H₃₂O₉ and 3C₃₁H₃₇BrO₁₀.0.76C₂H₆O

 

Methyl 12-Acetyl-9-methyl-11-thioxo-8-oxa-10,12-diazatricyclo[7.3.1.0^2,7]trideca-2,4,6-triene-13-carboxylate

V. Kettmann and J. Svetlík

Formula: C₁₅H₁₆N₂O₄S

 

The Cone Conformer of a Tetrakis(methylthio)tetrapropoxycalix[4]arene

T. M. Schultz, R. G. Hazell and M. Larsen

Formula: C₄₄H₅₆O₄S₄

 

A Benzannulated [5.3.1] Propellanone Related to the ABC Ring System of Taxol^TM

M. F. Mackay, M. G. Banwell and J. R. Phyland

Formula: C₁₆H₁₆Br₂O₂

 

4,4'-Azinodimethyldipyridinium Diperchlorate, C₁₂H₁₂N₄²⁺.2ClO₄^-

W. Chen, C.-M. Liu, D.-G. Li and X.-Z. You

Formula: C₁₂H₁₂N₄²⁺.2ClO₄^-

 

(1,2,3,6,7,8,9,13)-9,13-Dibromo-11-methyl-14,15-dioxa-11-azapentacyclo[6.5.1.1^3,6.0^2,7.0^9,13]pentadec-4-ene-10,12-dione

R. N. Warrener, L. Maksimovic and C. H. L. Kennard

Formula: C₁₃H₁₁Br₂NO₄

 

(1R,2R)-4-Methylurazole--D-pyranosyl-2-deoxyriboside from Reaction of 4-Methylurazole with 2-Deoxy-D-ribose

C. Y. Meyers, Y. Hou, V. M. Kolb and P. D. Robinson

Formula: C₈H₁₃N₃O₅

 

Quininium (S)-Mandelate

A. B. Gjerløv and S. Larsen

Formula: C₂₀H₂₅N₂O₂⁺.C₈H₇O₃^-

 

6-Hydroxyvouacapan-7,17-lactone

O. Abrahão-Junior, M. T. doP. Gambardella, S. G. Ruggiero, T. M. Sacramento, G. M. Stefani and D. Pilo-Veloso

Formula: C₂₀H₂₆O₄

 

Relative and Absolute Configuration of Aloperine

A. D. Brosius, J. W. Ziller and Q. Zhang

Formula: C₁₅H₂₄N₂ and C₁₅H₂₆N₂²⁺.2Cl^-.H₂O

 

3,3,6,6-Tetramethyl-9-(2-phenylethyl)-3,4,6,7,9,10-hexahydro-1,8(2H,5H)-acridinedione

K. Gunasekaran, D. Velmurugan and P. Murugan

Formula: C₂₅H₃₁NO₂

 

2H-1-Benzopyrans. II. 4-Chloro-3-methoxycarbonyl-2-dimethoxyphosphoryl-2H-1-benzopyran, (I), and 4-Chloro-2-dimethoxyphosphoryl-2H-1-benzopyran, (II)

T. A. Olszak, M. J. Grabowski, A. Stepien, R. Modranka and K. Kostka

Formula: C₁₃H₁₄ClO₆P and C₁₁H₁₂ClO₄P

Copyright © International Union of Crystallography
IUCr Webmaster