Acta Crystallographica Section C

Crystal Structure Communications

Volume 57, Part 10 (October 2001)

Acta Cryst. (2001). C57, 1174-1176 [doi:10.1107/S0108270101008216]

Short intramolecular SO interactions in S-substituted 2-mercaptoacetophenones

T. Creed, R. Leardini, H. McNab, D. Nanni, I. S. Nicolson, A. Parkin and S. Parsons

Abstract: The non-bonded SO intramolecular interactions in the title compounds 2-(phenylthio)acetophenone {IUPAC: 2-[2-(phenylsulfanyl)phenyl]ethanone}, C₁₄H₁₂OS, and 2-(benzylthio)acetophenone {IUPAC: 2-[2-(benzylsulfanyl)phenyl]ethanone}, C₁₅H₁₄OS, are unusually short, indicating the contribution of heterocyclic oxathiole-type resonance structures to the overall bonding.

Formula: C₁₄H₁₂OS and C₁₅H₁₄OS

Online 12 October 2001


	Structure factor file (CIF format) (101.8 kbytes) Contains datablock II

	Structure factor file (CIF format) (88.2 kbytes) Contains datablock III

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