Acta Crystallographica Section C

Crystal Structure Communications

Volume 58, Part 6 (June 2002)



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Acta Cryst. (2002). C58, o333-o335    [doi:10.1107/S0108270102006650]

(\pm)-Tartaric acid

P. E. Luner, A. D. Patel and D. C. Swenson

Abstract: (\pm)-Tartaric acid, C4H6O6, crystallized from ethanol in space group P\overline 1. The structure is characterized by five hydrogen bonds, including the formation of a centrosymmetric carboxylic acid dimer which forms infinite chains along the body diagonal. These chains form sheets via hydrogen bonding between [alpha]-hydroxyl groups. The sheets are connected through a bifurcated hydrogen bond. Structural comparisons are made with homochiral (2R,3R)-(+)-tartaric acid.

Formula: C4H6O6

Online 21 May 2002


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Comparison of theoretical X-ray powder diffraction pattern for (I) with the expected pattern of the bulk sample. Expected reflections are shown as verticle lines.


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