Acta Crystallographica Section C

Crystal Structure Communications

Volume 58, Part 8 (August 2002)

Acta Cryst. (2002). C58, m455-m458 [doi:10.1107/S0108270102012404]

Bis(1,10-phenanthroline)(thiosulfato)manganese(II) methanol solvate and catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline)manganese(II)]--thiosulfato]

E. Freire, S. Baggio, J. C. Muñoz and R. Baggio

Abstract: The structure of bis(1,10-phenanthroline- [bold kappa] ²N,N')(thiosulfato-²O:S)manganese(II) methanol solvate, [Mn(S₂O₃)(C₁₂H₈N₂)₂]·CH₃OH, is made up of Mn²⁺ centers coordinated to two bidentate phenanthroline (phen) groups and an S,O-chelating thiosulfate anion, forming monomeric entities. The structure of catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline- [bold kappa] ²N,N')manganese(II)]- [bold mu] -thiosulfato-²O:S], [Mn(S₂O₃)(C₁₄H₁₂N₂)(H₂O)₂]_n, is polymeric, consisting of Mn(dmph)(H₂O)₂ units (dmph is 2,9-dimethyl-1,10-phenanthroline) linked by thiosulfate anions acting in an S,O-chelating manner.

Formula: [Mn(S₂O₃)(C₁₂H₈N₂)₂]·CH₄O and [Mn(S₂O₃)(C₁₄H₁₂N₂)(H₂O)₂]

Online 31 July 2002


	Structure factor file (CIF format) (259.7 kbytes) Contains datablock I

	Structure factor file (CIF format) (175.3 kbytes) Contains datablock II

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