Acta Cryst. (2002). C58, i114-i118  [ doi:10.1107/S0108270102012532 ]

Bis(trichlorophosphine)iminium salts, [Cl₃P=N=PCl₃]⁺, with transition metal halide counter-ions

E. Rivard, A. R. McWilliams, A. J. Lough and I. Manners

Synopsis: Each of the four title structures contains discrete [Cl₃P=N=PCl₃]⁺ cations and metal halide anions. The [NbCl₆] and [TaCl₆] compounds are isostructural.

Formula: (Cl₆NP₂)[NbCl₆], (Cl₆NP₂)[TaCl₆], (Cl₆NP₂)[Ti₂Cl₉] and (Cl₆NP₂)₂[Zr₂Cl₁₀]

Online 10 August 2002

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