Acta Crystallographica Section C

Crystal Structure Communications

Volume 58, Part 11 (November 2002)

Acta Cryst. (2002). C58, m545-m548    [doi:10.1107/S0108270102018218]

(R)-Di--acetato-²O:O'-bis{[2-(1-aminoethyl)phenyl-²C¹,N]palladium(II)}, (R)-di--chloro-bis{[2-(1-aminoethyl)phenyl-²C¹,N]palladium(II)} and [SP-4-4]-(R)-[2-(1-aminoethyl)phenyl-²C¹,N]chloro(pyridine-N)palladium(II)

B. Calmuschi and U. Englert

Abstract: The title complexes, [Pd₂(C₈H₁₀N)₂(C₂H₃O₂)₂], (I), [Pd₂(C₈H₁₀N)₂Cl₂], (II), and [Pd(C₈H₁₀N)Cl(C₅H₅N)], (III), respectively, have been prepared as intermediates and the final product of a cyclopalladation reaction sequence, and their structures studied by single-crystal X-ray diffraction. Complexes (I) and (II) represent the first structurally characterized dinuclear cyclopalladation products of primary amines. For (I) and (III), pseudosymmetry relates two independent molecules in the asymmetric unit.

Formula: [Pd₂(C₈H₁₀N)₂(C₂H₃O₂)₂], [Pd₂(C₈H₁₀N)₂Cl₂] and [Pd(C₈H₁₀N)Cl(C₅H₅N)]

Online 31 October 2002

	Structure factor file (CIF format) (549.3 kbytes) Contains datablock I
	Structure factor file (CIF format) (215.1 kbytes) Contains datablock II
	Structure factor file (CIF format) (329.5 kbytes) Contains datablock III

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