Acta Crystallographica Section C

Crystal Structure Communications

Volume 58, Part 12 (December 2002)



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Acta Cryst. (2002). C58, i161-i163    [doi:10.1107/S0108270102017961]

Polymorphism in Cs[AgZn(NCS)4]

M. Günes and J. Valkonen

Abstract: The title compound, caesium silver zinc tetrathiocyanate, crystallizes in two polymorphic forms, in space groups P21/n and C2/c. Both structures form a continuous three-dimensional network. The structure in C2/c contains a delocalized Ag atom in a binuclear-like anion, where two [Ag(NCS)4] units (delocalized Ag as an average) share two common NCS- ligands.

Formula: Two polymorphs of Cs[AgZn(NCS)4]

Online 8 November 2002


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