Acta Crystallographica Section C

Crystal Structure Communications

Volume 59, Part 12 (December 2003)

metal-organic compounds

dn1033 scheme

Acta Cryst. (2003). C59, m526-m529 [ doi:10.1107/S0108270103024272 ]

Isomorphous dichloro- and dibromo(2-methyl-2-phenylpropyl)phenylstannane, both displaying the same intramolecular - interaction at 120 K

J. A. S. Bomfim, C. A. L. Filgueiras, R. A. Howie, J. M. S. Skakle and J. L. Wardell

Abstract: The title compounds, dichloro- and dibromoneophylphenyltin, [SnCl₂(C₆H₅)(C₁₀H₁₃)] and [SnBr₂(C₆H₅)(C₁₀H₁₃)], respectively, are remarkable for the `U' shape of the molecules, whereby the two phenyl groups are brought face-to-face in an arrangement that permits intermolecular C-H [pi] bonds to connect the molecules into layers parallel to (100). Intermolecular Sn-halide bonds are notably absent from the structures.

Formula: [SnCl₂(C₆H₅)(C₁₀H₁₃)] and [SnBr₂(C₆H₅)(C₁₀H₁₃)]


	Structure factor file (CIF format) (165.5 kbytes) Contains datablock I

	Structure factor file (CIF format) (184.9 kbytes) Contains datablock II

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