Acta Crystallographica Section C

Crystal Structure Communications

Volume 60, Part 1 (January 2004)


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Acta Cryst. (2004). C60, m13-m15    [doi:10.1107/S0108270103026830]

AgI and CuI binuclear macrocyclic complexes with 1-(3-pyridyl)ethanone oxime

I. Socorro, A. Neels and H. Stoeckli-Evans

Abstract: Bis[[bold mu]-1-(3-pyridyl)ethanone oxime-[bold kappa]2N:N']bis[nitratosilver(I)], [Ag2(NO3)2(C7H8N2O)2], crystallizes as a centrosymmetric binuclear macrocylic complex containing silver(I) ions bridged by the organic 1-(3-pyridyl)ethanone oxime ligand. The ligand coordinates via the pyridine and the oxime N atoms. A similar metal-ligand arrangement was found in the copper(I) complex catena-poly[[bis[[bold mu]-1-(3-pyridyl)ethanone oxime-[bold kappa]2N:N']dicopper(I)]-di-[bold mu]-iodo], [Cu2I2(C7H8N2O)2]n, but here the centrosymmetric macrocycles are connected by double anion bridges, resulting in the formation of a one-dimensional coordination polymer.

Formula: [Ag2(NO3)2(C7H8N2O)2] and [Cu2I2(C7H8N2O)2]

Online 6 December 2003

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