Crystal Structure Communications

 

Acta Cryst. (2004). C60, i11-i13  [ doi:10.1107/S0108270103026623 ]

K₄VP₂S₉

A. Gutzmann, C. Näther and W. Bensch

Synopsis: The crystal structure of the title compound, prepared by reacting a mixture of K₂S₃, VP, P₄S₃ and S, consists of discrete [VS(PS₄)₂]^4- anions, which are stacked along the direction of the crystallographic b axis and separated by K⁺ cations. In the anion, the V atom is connected to five S atoms within a square pyramid. The VS₅ group shares common edges with two bidentate [PS₄] tetrahedra.

Formula: K₄VP₂S₉

Online 17 January 2004

 

Acta Cryst. (2004). C60, i14-i16  [ doi:10.1107/S0108270103029056 ]

In_1.06Ho_0.94Ge₂O₇: a thortveitite-type compound

E. A. Juarez-Arellano, I. Rosales, A. Oliver, J. L. Ruvalcaba, R. E. Carbonio, L. Bucio and E. Orozco

Synopsis: The crystal structure of a new indium holmium germanate, In_1.06Ho_0.94Ge₂O₇, belonging to the thortveitite structure type, is reported. The In³⁺ and Ho³⁺ cations occupy the same octahedral site, forming an hexagonal arrangement on the ab plane. In their turn, the hexagonal arrangements of (In/Ho)O₆ octahedral layers are held together by sheets of isolated diortho groups comprised of double tetrahedra sharing a common vertex.

Formula: In_1.06Ho_0.94Ge₂O₇

Online 17 January 2004

 

Acta Cryst. (2004). C60, i17-i19  [ doi:10.1107/S0108270103029068 ]

Cs₂Cr₄O₁₃: a new structure type among alkali tetrachromates

U. Kolitsch

Synopsis: Cs₂Cr₄O₁₃ contains a [Cr₄O₁₃]^2- anion with a zigzag-like structure, built from four corner-linked CrO₄ tetrahedra, and has a structure type previously unknown among alkali tetrachromates.

Formula: Cs₂Cr₄O₁₃

Online 31 January 2004

 

Acta Cryst. (2004). C60, i20-i22  [ doi:10.1107/S0108270103025666 ]

The high-temperature modification of zinc catena-polyphosphate, -Zn(PO₃)₂

M. Weil

Synopsis: Single crystals of the high-temperature modification of zinc catena-polyphosphate, -Zn(PO₃)₂, were grown from a melt and quenched from 1093  K to room temperature. The structure is built of corrugated (PO₃) polyphosphate chains linked by slightly distorted [ZnO₄] tetrahedra into a three-dimensional network.

Formula: Zn(PO₃)₂

Online 31 January 2004

 

Acta Cryst. (2004). C60, m39-m41  [ doi:10.1107/S0108270103027847 ]

Poly[[bis(1H-benzimidazole-N³)cadmium(II)]--aqua--succinato-²O¹:O⁴]

B.-X. Liu and D.-J. Xu

Formula: [Cd(C₄H₄O₄)(C₇H₆N₂)₂(H₂O)]

Online 10 January 2004

 

Acta Cryst. (2004). C60, m42-m43  [ doi:10.1107/S0108270103027902 ]

An oxo-bridged centrosymmetric tetranuclear titanium compound

T. Kemmitt, G. J. Gainsford and N. I. Al-Salim

Formula: [Ti₄(C₅H₁₁NO₂)₂(C₄H₉O)₈O₂]

Online 10 January 2004

 

Acta Cryst. (2004). C60, m44-m46  [ doi:10.1107/S0108270103028014 ]

A new complex of HgBr₂ and pyrimidine-2-thione: (pyrimidine-2-thionato-S)(pyrimidinium-2-thionato-S)mercury(II) tetrabromomercury(II)

D. Matkovic-Calogovic, D. Mrvos-Sermek, Z. Popovic and Z. Soldin

Formula: [Hg(C₄H₄N₂S)(C₄H₃N₂S)]₂[HgBr₄]

Online 10 January 2004

 

Acta Cryst. (2004). C60, m47-m50  [ doi:10.1107/S0108270103028130 ]

(2,2'-Bipyridine-²N,N')(1,1-cyclobutanedicarboxylato-²O,O')palladium(II), (1,1-cyclobutanedicarboxylato-²O,O')(1,10-phenanthroline-²N,N')palladium(II) monohydrate and (1,1-cyclobutanedicarboxylato-²O,O')(1,10-phenanthroline-²N,N')palladium(II) dihydrate

Y. Muranishi and N. Okabe

Formula: [Pd(C₆H₆O₄)(C₁₀H₈N₂)], [Pd(C₆H₆O₄)(C₁₂H₈N₂)]·H₂O and [Pd(C₆H₆O₄)(C₁₂H₈N₂)]·2H₂O

Online 10 January 2004

 

Acta Cryst. (2004). C60, m51-m54  [ doi:10.1107/S0108270103028385 ]

Bis[bis(pyrimidin-2-yl-N)amine](dicyanamido-N¹)(trifluoromethanesulfonato-O)copper(II) ethanol hemisolvate forms a hydrogen-bonded chain

H. Kooijman, A. L. Spek, G. A. van Albada, P. Gamez and J. Reedijk

Formula: [Cu(CF₃SO₃)(C₂N₃)(C₈H₇N₅)₂]·0.5C₂H₆O

Online 10 January 2004

 

Acta Cryst. (2004). C60, m55-m56  [ doi:10.1107/S0108270103028270 ]

Bis(benzylammonium) hexachlorotin(IV)

M. Rademeyer

Formula: (C₇H₁₀N)₂[SnCl₆]

Online 10 January 2004

 

Acta Cryst. (2004). C60, m57-m59  [ doi:10.1107/S0108270103028051 ]

[5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinato]iron(II) benzene disolvate

Y. Oh, B.-C. Shin, D. Swenson, H. M. Goff and S. K. Kang

Formula: [Fe(C₄₄H₈F₂₀N₄)]·2C₆H₆

Online 10 January 2004

 

Acta Cryst. (2004). C60, m60-m62  [ doi:10.1107/S0108270103028464 ]

Tetrameric dichloro(trimethylammonio-p-toluenesulfonamidate)mercury(II)

K. W. Muir, D. G. Morris and C. O. W. Chii

Formula: [Hg₄Cl₈(C₁₀H₁₆N₂O₂S)₄]

Online 17 January 2004

 

Acta Cryst. (2004). C60, m63-m64  [ doi:10.1107/S0108270103028907 ]

catena-Poly[bis[(2,2-bipyridine-²N,N')copper(II)]-₄-1,2,4,5-benzenetetracarboxylato-⁴O¹:O²:O³:O⁴]

H.-P. Xiao, X.-H. Li, J.-X. Yuan and M.-L. Hu

Formula: [Cu₂(C₁₀H₂O₈)(C₁₀H₈N₂)₂]

Online 17 January 2004

 

Acta Cryst. (2004). C60, m65-m68  [ doi:10.1107/S0108270103028841 ]

Bis[tris(2,2'-bipyridine-²N,N')ruthenium(II)] hexacyanoferrate(III) chloride octahydrate

K. Sakai, Y. Uchida, T. Kajiwara and T. Ito

Formula: [Ru(C₁₀H₈N₂)₃]₂[Fe(CN)₆]Cl·8H₂O

Online 17 January 2004

 

Acta Cryst. (2004). C60, m69-m72  [ doi:10.1107/S0108270103029500 ]

Bis(2,2'-bipyridine-²N,N')(1,10-phenanthroline-²N,N')ruthenium(II) tetracyanoplatinate(II)

K. Sakai and Y. Miyabe

Formula: [Ru(C₁₀H₈N₂)₂(C₁₂H₈N₂)][Pt(CN)₄]

Online 31 January 2004

 

Acta Cryst. (2004). C60, m73-m75  [ doi:10.1107/S0108270104000216 ]

The Zn²⁺ salt of pamidronate: a role for water in the metal-cation binding properties of bisphosphonates

D. Fernández, G. Polla, D. Vega and J. A. Ellena

Formula: Zn²⁺·2C₃H₁₀NO₇P₂^-·2H₂O

Online 31 January 2004

 

Acta Cryst. (2004). C60, m76-m78  [ doi:10.1107/S0108270103029573 ]

Poly[lead(II)-₂-aqua-₄-terephthalato]

S. H. Dale, M. R. J. Elsegood and S. Kainth

Formula: [Pb(C₈H₄O₄)(H₂O)]

Online 31 January 2004

 

Acta Cryst. (2004). C60, m79-m81  [ doi:10.1107/S0108270104000186 ]

A novel five-coordinate cadmium phenanthroline thiosulfate

M. Harvey, S. Baggio, H. Pardo and R. Baggio

Formula: [Cd(S₂O₃)(C₁₂H₈N₂)]

Online 31 January 2004

 

Acta Cryst. (2004). C60, m82-m84  [ doi:10.1107/S0108270104000204 ]

Chloro{2,2'-[(1S,2S)-1,2-diphenyl-1,2-ethanediylbis(nitrilomethylidyne)]diphenolato-⁴O,N,N',O'}(ethanol-O)manganese(III)

I. V. Korendovych and E. V. Rybak-Akimova

Formula: [MnCl(C₂₈H₂₂N₂O₂)(C₂H₆O)]

Online 31 January 2004

 

Acta Cryst. (2004). C60, m85-m87  [ doi:10.1107/S010827010302883X ]

Tetra--benzoato-⁸O:O'-bis({1-[(3,4-dimethoxyphenyl)methyl]-6,7-dimethoxyisoquinoline-N}zinc(II)): the first crystal structure with papaverine as a ligand

V. Zelenák, M. Sabo, W. Massa and J. Cernák

Formula: [Zn₂(C₇H₅O₂)₄(C₂₀H₂₁NO₄)₂]

Online 31 January 2004

 

Acta Cryst. (2004). C60, m88-m90  [ doi:10.1107/S0108270104000344 ]

Diisopropylphosphitocobalamin-acetone-water (1/3.48/7.56)

S. M. Chemaly, H. M. Marques and C. B. Perry

Synopsis: The diisopropylphosphite ligand coordinates to the Co^III atom via its P atom. The crystal structure is isomorphous with that of other cobalamins that adopt packing type II, with a Co-P bond length [2.227  (1)  Å] similar to that found in other phosphitocobalamins.

Formula: [Co(C₆₈H₁₀₂N₁₃O₁₇P₂)]·3.48C₃H₆O·7.56H₂O

Online 31 January 2004

 

Acta Cryst. (2004). C60, m91-m93  [ doi:10.1107/S0108270104000411 ]

A polymeric ladder complex: catena-poly[[[-4,4'-bipyridyl-bis[aqua(p-aminobenzoato)copper(II)]]-di--4,4'-bipyridyl] dinitrate tetrahydrate]

D.-H. Hu, W. Huang, K. Cui, Y.-Z. Li, S.-H. Gou and J.-L. Yan

Formula: [Cu₂(C₇H₆NO₂)₂(C₁₀H₈N₂)₃(H₂O)₂](NO₃)₂·4H₂O

Online 31 January 2004

 

Acta Cryst. (2004). C60, m94-m96  [ doi:10.1107/S0108270104000605 ]

Tetrakis(tetrahydrofuran-O)lithium mer-tris(carbazolyl-N)-trans-dichloro(tetrahydrofuran-O)zirconate

C. L. Nygren, M. E. T. Bragg and J. F. C. Turner

Formula: [Li(C₄H₈O)₄][ZrCl₂(C₁₂H₈N)₃(C₄H₈O)]

Online 31 January 2004

 

Acta Cryst. (2004). C60, m97-m100  [ doi:10.1107/S0108270104000198 ]

catena-Poly[[bis(hexafluoroacetylacetonato-²O,O')zinc(II)]--4,4'-bipyridine-²N:N']

J. Granifo, M. T. Garland and R. Baggio

Formula: [Zn(C₅HF₆O₂)₂(C₁₀H₈N₂)]

Online 31 January 2004

 

Acta Cryst. (2004). C60, o103-o106  [ doi:10.1107/S0108270103027197 ]

2,4-Dinitrophenylhydrazones of 2,4-dihydroxybenzaldehyde, 2,4-dihydroxyacetophenone and 2,4-dihydroxybenzophenone

R. G. Baughman, K. L. Martin, R. K. Singh and J. O. Stoffer

Formula: C₁₃H₁₀N₄O₆·C₃H₇NO, C₁₄H₁₂N₄O₆·C₃H₇NO and C₁₉H₁₄N₄O₆·C₄H₉NO

Online 10 January 2004

 

Acta Cryst. (2004). C60, o107-o109  [ doi:10.1107/S0108270103027859 ]

5,5'-Di-tert-butyl-2,2'-dihydroxy-3,3'-methylenedibenzaldehyde and 6,6'-di-tert-butyl-8,8'-methylenebis(spiro[4H-1,3-benzodioxin-2,1'-cyclohexane])

B. Masci, S. Levi Mortera, L. Seralessandri and P. Thuéry

Formula: C₂₃H₂₈O₄ and C₃₅H₄₈O₄

Online 10 January 2004

 

Acta Cryst. (2004). C60, o110-o112  [ doi:10.1107/S0108270103028038 ]

16-(4-Isopropylbenzylidene)androst-4-ene-3,17-dione

S. Thamotharan, V. Parthasarathi, S. Dubey, D. P. Jindal and A. Linden

Formula: C₂₉H₃₆O₂

Online 10 January 2004

 

Acta Cryst. (2004). C60, o113-o114  [ doi:10.1107/S0108270103028282 ]

2,2'-Bipyridinium(1+) bromide monohydrate

R. J. Bowen, M. A. Fernandes, P. W. Gitari and M. Layh

Formula: C₁₀H₉N₂⁺·Br^-·H₂O

Online 10 January 2004

 

Acta Cryst. (2004). C60, o115-o117  [ doi:10.1107/S0108270103028178 ]

N¹-(2,6-Dimethylphenyl)-N²-hydroxy--oxo--phenylacetamidine

S. Soylu, M. Tas, H. Saraçoglu, H. Bati, N. Çaliskan and O. Büyükgüngör

Formula: C₁₆H₁₆N₂O₂

Online 10 January 2004

 

Acta Cryst. (2004). C60, o118-o119  [ doi:10.1107/S0108270103027835 ]

N-(2-Fluoroethyl)-3-(4-iodophenyl)-8-methyl-8-azabicyclo[3.2.1]octane-2-carboxamide: a new cocaine derivative with equatorially attached ligands

B. Krebs and U. Flörke

Formula: C₁₇H₂₂FIN₂O

Online 10 January 2004

 

Acta Cryst. (2004). C60, o120-o124  [ doi:10.1107/S0108270103027914 ]

-Stacked hydrogen-bonded dimers in 2-(2-nitrophenylaminocarbonyl)benzoic acid, and hydrogen-bonded sheets in orthorhombic and monoclinic polymorphs of 2-(4-nitrophenylaminocarbonyl)benzoic acid

C. Glidewell, J. N. Low, J. M. S. Skakle and J. L. Wardell

Formula: Isomers and polymorphs of C₁₄H₁₀N₂O₅

Online 10 January 2004

 

Acta Cryst. (2004). C60, o125-o126  [ doi:10.1107/S0108270103029421 ]

4-Chloro-N-(trimethylammonio)benzamide chloride monohydrate

K. W. Muir, D. G. Morris and C. O. W. Chii

Formula: C₁₀H₁₄ClN₂O⁺·Cl^-·H₂O

Online 17 January 2004

 

Acta Cryst. (2004). C60, o127-o129  [ doi:10.1107/S0108270103029196 ]

Twinning by merohedry in cyclohexanone oxime: a revised structure

M. Lutz, A. L. Spek, R. Dabirian, C. A. van Walree and L. W. Jenneskens

Formula: Two refinements of C₆H₁₁NO

Online 17 January 2004

 

Acta Cryst. (2004). C60, o130-o132  [ doi:10.1107/S010827010302866X ]

6-[3-Hydroxy-17-oxoestra-1,3,5(10)-trien-7-yl]hexanenitrile

C. Yamamoto, T. Matsumoto, M. Watanabe, E. M. S. Hitzer, S. Mataka and T. Thiemann

Formula: C₂₄H₃₁NO₂

Online 17 January 2004

 

Acta Cryst. (2004). C60, o133-o135  [ doi:10.1107/S010827010302941X ]

4-[(2-Chlorophenyl)diazenyl]-6-methoxy-2-{[tris(hydroxymethyl)methyl]aminomethylene}cyclohexa-3,5-dien-1(2H)-one

C. C. Ersanli, Ç. Albayrak, M. Odabasoglu, C. Thöne and A. Erdönmez

Formula: C₁₈H₂₀ClN₃O₅

Online 17 January 2004

 

Acta Cryst. (2004). C60, o136-o139  [ doi:10.1107/S0108270103027586 ]

3-Oxa-6,8-diaza-1,2:4,5-dibenzocycloocta-1,4-dien-7-one: a three-dimensional network assembled by hydrogen-bonding, - and edge-to-face interactions

V. Böhmer, D. Meshcheryakov, I. Thondorf and M. Bolte

Formula: C₁₃H₁₀N₂O₂

Online 17 January 2004

 

Acta Cryst. (2004). C60, o140-o142  [ doi:10.1107/S0108270103029329 ]

4-Oxocyclohexanecarboxylic acid: hydrogen bonding in the monohydrate of a -keto acid

A. Barcon, A. P. J. Brunskill, H. W. Thompson and R. A. Lalancette

Formula: C₇H₁₀O₃·H₂O

Online 31 January 2004

 

Acta Cryst. (2004). C60, o143-o145  [ doi:10.1107/S0108270103029433 ]

3-Butyl-1-(5-nitrobenzo[c][1,2]thiazol-3-yl)-3-phenyltriazene

V. Kettmann, J. Lokaj, J. Kozísek, J. Prikryl and V. Machácek

Formula: C₁₇H₁₇N₅O₂S

Online 31 January 2004

 

Acta Cryst. (2004). C60, o146-o148  [ doi:10.1107/S0108270103026775 ]

Monitoring structural transformations in crystals. 7. 1-Chloroanthracene and its photodimer

I. Turowska-Tyrk and K. Grzesniak

Formula: C₁₄H₉Cl and C₂₈H₁₈Cl₂

Online 31 January 2004

 

Acta Cryst. (2004). C60, o149-o151  [ doi:10.1107/S0108270103028154 ]

tert-Butyl 5-methoxy-3-pentylindole-1-carboxylate

J. F. Gallagher, C. M. Coleman and D. F. O'Shea

Formula: C₁₉H₂₇NO₃

Online 31 January 2004

 

Acta Cryst. (2004). C60, o152-o155  [ doi:10.1107/S010827010400023X ]

Two triclinic polymorphs of 2,3,5,6-tetrakis(naphthalen-2-ylsulfanylmethyl)pyrazine

J. Pacifico and H. Stoeckli-Evans

Formula: Two polymorphs of C₄₈H₃₆N₂S₄

Online 31 January 2004

 

Acta Cryst. (2004). C60, o156-o157  [ doi:10.1107/S010827010400040X ]

sp-9-(o-Methylphenyl)fluorene

C. Y. Meyers, P. D. Robinson and A. W. McLean

Formula: C₂₀H₁₆

Online 31 January 2004

 

Acta Cryst. (2004). C60, o158-o160  [ doi:10.1107/S0108270103029159 ]

An aza-steroidal [17,16-c]pyrazole derivative: 2'-(p-fluorophenyl)-17a-aza-2'H-pyrazolo[4',3':16,17]-D-homoandrost-4-en-3-one

S. Thamotharan, V. Parthasarathi, R. Gupta, D. P. Jindal and A. Linden

Formula: C₂₆H₃₀FN₃O

Online 31 January 2004

 

Acta Cryst. (2004). C60, o161-o162  [ doi:10.1107/S0108270103028452 ]

16-Cyano-13-(5-methyl-1,3,4-oxadiazol-2-yl)-13,16-seco-17-norandrost-5-en-3-yl acetate

S. Thamotharan, V. Parthasarathi, R. Gupta, D. P. Jindal and A. Linden

Formula: C₂₃H₃₁N₃O₃

Online 31 January 2004