Acta Crystallographica Section C

Crystal Structure Communications

Volume 60, Part 4 (April 2004)



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Acta Cryst. (2004). C60, o270-o272    [doi:10.1107/S0108270104004299]

(Cyclohexylideneamino)oxyacetic acid and [chloro(phenyl)methyleneamino]oxyacetic acid: hydrogen-bonded R_2^2(8) dimers and aromatic [bold pi]-[bold pi] stacking interactions

C. Glidewell, J. N. Low, J. M. S. Skakle and J. L. Wardell

Abstract: Molecules of (cyclohexylideneamino)oxyacetic acid, C8H13NO3, (I), are linked into centrosymmetric dimers by pairs of O-H...O hydrogen bonds [H...O  =  1.84  Å, O...O  = 2.6782  (12)  Å and O-H...O  =  178°]. In [chloro(phenyl)methyleneamino]oxyacetic acid, C9H8ClNO3, (II), the molecules are similarly linked into centrosymmetric dimers by pairs of O-H...O hydrogen bonds [H...O  = 1.79  Å, O...O  =  2.6329  (17)  Å and O-H...O  =  176°], and these dimers are weakly linked into chains by a single type of aromatic [bold pi]-[bold pi] stacking interaction.

Formula: C9H8ClNO3 and C8H13NO3

Online 20 March 2004


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Structure factor file (CIF format) (95.7 kbytes)
Contains datablock I


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Structure factor file (CIF format) (104.9 kbytes)
Contains datablock II


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