





Acta Cryst. (2004). C60, i63-i65 [doi:10.1107/S0108270104008790]
Abstract: The crystal structures of dicaesium nickel disilver hexathiocyanate dihydrate, Cs2NiAg2(SCN)6·2H2O, (I), and caesium nickel trithiocyanate, CsNi(SCN)3, (II), have been determined by single-crystal X-ray diffraction at 273 K. Compounds (I) and (II) are monoclinic, with P21/c and P21/n symmetry, respectively. In (I), the Ni atom lies on an inversion centre; in (II), there are two independent Ni atoms, each of which lies on an inversion centre. The coordination polyhedra and the bonding schemes in the structures are discussed.
Formula: Cs2NiAg2(SCN)6·2H2O and CsNi(SCN)3
Online 22 June 2004
![]() ![]() Structure factor file (CIF format) (205.1 kbytes) | |
![]() ![]() Structure factor file (CIF format) (170.1 kbytes) | |
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