Acta Crystallographica Section C

Crystal Structure Communications

Volume 60, Part 7 (July 2004)



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Acta Cryst. (2004). C60, i63-i65    [doi:10.1107/S0108270104008790]

Thiocyanates of nickel and caesium: Cs2NiAg2(SCN)6·2H2O and CsNi(SCN)3

M. Fleck

Abstract: The crystal structures of dicaesium nickel disilver hexathiocyanate dihydrate, Cs2NiAg2(SCN)6·2H2O, (I), and caesium nickel trithiocyanate, CsNi(SCN)3, (II), have been determined by single-crystal X-ray diffraction at 273  K. Compounds (I) and (II) are monoclinic, with P21/c and P21/n symmetry, respectively. In (I), the Ni atom lies on an inversion centre; in (II), there are two independent Ni atoms, each of which lies on an inversion centre. The coordination polyhedra and the bonding schemes in the structures are discussed.

Formula: Cs2NiAg2(SCN)6·2H2O and CsNi(SCN)3

Online 22 June 2004


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Structure factor file (CIF format) (205.1 kbytes)
Contains datablock I


hkldisplay filedownload file

Structure factor file (CIF format) (170.1 kbytes)
Contains datablock I


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