Acta Cryst. (2004). C60, m345-m347 [doi:10.1107/S0108270104012636]
Abstract: The crystal structures of the title complexes, namely trans-bis(isoquinoline-3-carboxylato-![[bold kappa]](/logos/entities/kappa_bdgif.gif)
2N,O)bis(methanol-O)cobalt(II), [Co(C10H6NO2)2(CH3OH)2], and the corresponding nickel(II) and copper(II) complexes, [Ni(C10H6NO2)2(CH3OH)2] and [Cu(C10H6NO2)2(CH3OH)2], are isomorphous and contain metal ions at centres of inversion. The three compounds have the same distorted octahedral coordination geometry, and each metal ion is bonded by two quinoline N atoms, two carboxylate O atoms and two methanol O atoms. Two isoquinoline-3-carboxylate ligands lie in trans positions, forming the equatorial plane, and the two methanol ligands occupy the axial positions. The complex molecules are linked together by O-H
O hydrogen bonds between the methanol ligands and neighbouring carboxylate groups.
Formula: [Co(C10H6NO2)2(CH4O)2], [Ni(C10H6NO2)2(CH4O)2] and [Cu(C10H6NO2)2(CH4O)2]
Online 22 June 2004
 |   Structure factor file (CIF format) (100.4 kbytes) |
| Structure factor file (CIF format) (110.7 kbytes) |
| Structure factor file (CIF format) (114.4 kbytes) |
To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.
The download button will force most browsers to prompt for a file name to store the data on your hard disk.
Where possible, images are represented by thumbnails.
Copyright © International Union of Crystallography
IUCr Webmaster