Acta Crystallographica Section C

Crystal Structure Communications

Volume 60, Part 7 (July 2004)



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Acta Cryst. (2004). C60, m305-m307    [doi:10.1107/S0108270104010893]

Bis[tris(pyridin-2-yl)methanol-[bold kappa]2N,N']palladium(II) dinitrate at 150 and 298  K

A. J. Canty, B. W. Skelton, P. R. Traill and A. H. White

Abstract: The title complex, [Pd{(py)3COH}2](NO3)2, where (py)3COH is tris(pyridin-2-yl)methanol (C16H13N3O), studied at 150 and 298  K, has the potentially tridentate ligands present as bidentate ligands, with the Pd atom at a centre of symmetry. At 150  K, the Pd-N distances are 2.022  (3) and 2.026  (3)  Å. The mean planes of the coordinated pyridine groups form dihedral angles of 42.1  (1) and 45.3  (1)° (at 150  K) with the coordination plane; the uncoordinated rings situated either side of the coordination plane form dihedral angles of 42.2  (1)° with it. The nitrate ions are regular and interact weakly with the hydroxyl group.

Formula: [Pd(C16H13N3O)2](NO3)2

Online 12 June 2004


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Structure factor file (CIF format) (277.2 kbytes)
Contains datablock I


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Structure factor file (CIF format) (333.6 kbytes)
Contains datablock II


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