Acta Crystallographica Section C

Crystal Structure Communications

Volume 60, Part 8 (August 2004)



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Acta Cryst. (2004). C60, m382-m385    [doi:10.1107/S0108270104014131]

Bis(acetato-[bold kappa]2O,O')(2,9-dimethyl-1,10-phenanthroline-[bold kappa]2N,N')mercury(II) in two differently hydrated crystal forms

M. A. Harvey, S. Baggio, A. Ibañez and R. Baggio

Abstract: Two differently hydrated crystal forms of the title compound, viz. bis(acetato-[bold kappa]2O,O')(2,9-dimethyl-1,10-phenanthroline-[bold kappa]2N,N')mercury(II), [Hg(C2H3O2)2(C14H12N2)] or [HgAc2(dmph)] [dmph is 2,3-dimethyl-1,10-phenantroline (neocuproine) and Ac is acetate], (I), and tris[bis(acetato-[bold kappa]2O,O')(2,9-dimethyl-1,10-phenanthroline-[bold kappa]2N,N')mercury(II)] hexadecahydrate, [Hg(C2H3O2)2(C14H12N2)]3·16H2O or [HgAc2(dmph)]3·16H2O, (II), are presented. Both structures are composed of very simple monomeric units, which act as the building blocks of complex packing schemes stabilized by a diversity of [bold pi]-[bold pi] and hydrogen-bonding interactions.

Formula: [Hg(C2H3O2)2(C14H12N2)] and [Hg(C2H3O2)2(C14H12N2)]3·16H2O

Online 21 July 2004


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Structure factor file (CIF format) (179.4 kbytes)
Contains datablock I


hkldisplay filedownload file

Structure factor file (CIF format) (732.6 kbytes)
Contains datablock II


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