Acta Crystallographica Section C

Crystal Structure Communications

Volume 61, Part 1 (January 2005)


organic compounds



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Acta Cryst. (2005). C61, o10-o14    [doi:10.1107/S0108270104028483]

Hydrogen-bonded sheets in (E)-2-nitrobenzaldehyde 4-nitrophenylhydrazone and a hydrogen-bonded framework structure in (E)-4-nitrobenzaldehyde 4-nitrophenylhydrazone

J. L. Wardell, J. M. S. Skakle, J. N. Low and C. Glidewell

Abstract: Molecules of (E)-2-nitrobenzaldehyde 4-nitrophenylhydrazone, C13H10N4O4, exhibit a strongly polarized molecular-electronic structure. The molecules are linked into sheets of some complexity, where pairs of hydrogen bonds act co-operatively to generate two independent substructures, each in the form of a chain of rings. In the isomeric compound (E)-4-nitrobenzaldehyde 4-nitrophenylhydrazone, the molecules exhibit orientational disorder; an extensive series of hydrogen bonds links the molecules into a continuous three-dimensional framework, whose formation is independent of the disorder.

Formula: C13H10N4O4


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