Acta Crystallographica Section C

Crystal Structure Communications

Volume 61, Part 3 (March 2005)

metal-organic compounds


HTML versionpdf versioncif file3d viewstructure factorssimilar papers buy article online

sq1194 scheme

Acta Cryst. (2005). C61, m151-m154    [doi:10.1107/S0108270105003446]

Tetrakis(1-ethyl-1H-1,2,4-triazole-[bold kappa]N4)bis(nitrato-[bold kappa]O)copper(II) and bis(nitrato-[bold kappa]O)tetrakis(1-propyl-1H-1,2,4-triazole-[bold kappa]N4)copper(II)

J. Zaleski, M. Gabryszewski and B. Zarychta

Abstract: The copper(II) environments for tetrakis(1-ethyl-1,2,4-triazole)dinitratocopper(II), [Cu(NO3)2(C4H7N3)4], and tetrakis(1-propyl-1,2,4-triazole)dinitratocopper(II), [Cu(NO3)2(C5H9N3)4], are distorted square bipyramidal. Both structures are centrosymmetric, with the copper(II) ions located at inversion centers coordinated by four N atoms of four triazole molecules and by two O atoms of two nitrate ions in an elongated octahedral geometry. This elongation is a result of the Jahn-Teller effect. The largest distortion is that of the N-Cu-O angles, which differ from 90° by 5.68  (10)° in the ethyl and 5.59  (8)° in the propyl derivative.

Formula: [Cu(NO3)2(C4H7N3)4] and [Cu(NO3)2(C5H9N3)4]

hkldisplay filedownload file

Structure factor file (CIF format) (117.2 kbytes)
Contains datablock I

hkldisplay filedownload file

Structure factor file (CIF format) (135.8 kbytes)
Contains datablock II

Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

other supplementary material

If the supplementary material that you require is not shown in the list above, it may only be available in our hard-copy archive. However, our policy is to progressively digitize old hard-copy supplementary documents where possible.

Please help us to work towards this goal by completing the form below. This will register your wish to receive a supplementary document, which we shall scan to create a PDF and then make available via the web to you and to other requestors in the future.

SUP

Please identify the article from which this was referenced, if known:


Journal Volume First Page 

Important: Please check carefully that the paper information (journal, volume and first page number) above corresponds to the SUP number you supplied.

Please supply some information about yourself:

Name
E-mail

Address

E-mail me when the PDF document is available so that I can download it.
Send the hard-copy print to me by normal mail

  
  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster