Acta Crystallographica Section C

Crystal Structure Communications

Volume 61, Part 5 (May 2005)

organic compounds

ta1464 scheme

Acta Cryst. (2005). C61, o303-o305 [doi:10.1107/S0108270105004373]

1,3-Bis(4-methylphenyl)triazene, 1-(4-chlorophenyl)-3-(4-fluorophenyl)triazene and 1-(4-fluorophenyl)-3-(4-methylphenyl)triazene

N. Karadayi, S. Çakmak, M. Odabasoglu and O. Büyükgüngör

Abstract: The title 4,4'-disubstituted diphenyl-1,3-triazines, C₁₄H₁₅N₃, (I), C₁₂H₉ClFN₃, (II), and C₁₃H₁₂FN₃, (III), each contain a triazene group (-N=N-NH-) having an extended conformation. The dihedral angles between the two benzene rings in (I), (II) and (III) are 4.3, 3.4 and 6.5°, respectively. The molecules are almost entirely planar, with maximum deviations from the mean planes of 0.1087 (2), -0.1072 (7) and 0.1401 (3) Å, respectively. In each compound, the molecules are linked by N-HN hydrogen bonds to form chains and pack similarly in the crystal structures.

Formula: C₁₄H₁₅N₃, C₁₂H₉ClFN₃ and C₁₃H₁₂FN₃


	Structure factor file (CIF format) (105.2 kbytes) Contains datablock I

	Structure factor file (CIF format) (103.9 kbytes) Contains datablock II

	Structure factor file (CIF format) (97.3 kbytes) Contains datablock III

Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

other supplementary material

If the supplementary material that you require is not shown in the list above, it may only be available in our hard-copy archive. However, our policy is to progressively digitize old hard-copy supplementary documents where possible.

Please help us to work towards this goal by completing the form below. This will register your wish to receive a supplementary document, which we shall scan to create a PDF and then make available via the web to you and to other requestors in the future.

Name
E-mail
Address