Acta Crystallographica Section C

Crystal Structure Communications

Volume 61, Part 11 (November 2005)

metal-organic compounds


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Acta Cryst. (2005). C61, m466-m468    [doi:10.1107/S0108270105030192]

Di-[mu]-acetato-bis{[2,4-dichloro-6-(2-pyridylmethyliminomethyl)phenolato]zinc(II)} and di-[mu]-thiocyanato-bis{[2,4-dichloro-6-(2-pyridylmethyliminomethyl)phenolato]copper(II)

Z.-L. You

Abstract: The two title complexes, [Zn2(C13H9Cl2N2O)2(C2H3O2)2], (I), and [Cu2(C13H9Cl2N2O)2(NCS)2], (II), are dinuclear Schiff base compounds. Both molecules are located on crystallographic centres of inversion. In (I), the ZnII atom is five-coordinated in a trigonal-bipyramidal coordination, with one imine N atom of one Schiff base and two acetate O atoms defining the basal plane, and one O atom and one pyridine N atom of the Schiff base occupying the axial positions, while in (II), the CuII atom is five-coordinated in a square-pyramidal coordination, with one O and two N atoms of one Schiff base and one terminal N atom of a bridging thiocyanate ligand defining the basal plane, and one terminal S atom of another bridging thiocyanate ligand occupying the apical position. The different bridging ligands lead to the different coordinations of the complexes.

Formula: [Zn2(C13H9Cl2N2O)2(C2H3O2)2] and [Zn2(C13H9Cl2N2O)2(NCS)2]

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Contains datablock II

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