Acta Crystallographica Section C

Crystal Structure Communications

Volume 62, Part 2 (February 2006)

metal-organic compounds

 

Bis[bis(3-phenylpyrazol-1-yl)(pyrazol-1-yl)methane]copper(II) bis(perchlorate) acetonitrile disolvate

M. S. Goodman, M. A. Goodman, A. Y. Kovalevsky, A. Y. Nazarenko and D. Pope

Abstract: The title copper(II) complex, [Cu(C₂₂H₁₈N₆)₂](ClO₄)₂·2C₂H₃N, comprises two neutral substituted tris(pyrazol-1-yl)methane ligands bonded to a central Cu^II ion, which is positioned on a crystallographic inversion center. Six Cu-N bonds are arranged in a distorted octahedral fashion. The unsubstituted pyrazole rings on each ligand are oriented trans with respect to each other, interdigitated with the two 3-phenylpyrazole rings of the other ligand.

Formula: [Cu(C₂₂H₁₈N₆)₂](ClO₄)₂·2C₂H₃N

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