Acta Crystallographica Section C

Crystal Structure Communications

Volume 62, Part 6 (June 2006)

metal-organic compounds

gd3013 scheme

Acta Cryst. (2006). C62, m223-m226 [ doi:10.1107/S0108270106013199 ]

Bis(1-methyl-1H-tetrazol-5-yl)diazene and two its copper(I) chloride complexes poly[[[-1,2-bis(1-methyl-1H-tetrazol-5-yl)diazene-⁴N',N⁴:N,N^4']dicopper(I)]-di--chloro] and catena-poly[[chlorocopper(I)]--1,2-bis(1-methyl-1H-tetrazol-5-yl)diazene-⁴N',N⁴:N,N^4']

A. S. Lyakhov, T. V. Serebryanskaya, P. N. Gaponik, S. V. Voitekhovich and L. S. Ivashkevich

Abstract: While bis(1-methyl-1H-tetrazol-5-yl)diazene, C₄H₆N₁₀, (I), has no crystallographically imposed symmetry, in the two title chlorocopper(I) complexes, [Cu₂Cl₂(C₄H₆N₁₀)]_n, (II), and [CuCl(C₄H₆N₁₀)]_n, (III), the organic ligands lie across centres of inversion; in (III), the Cu and Cl atoms additionally lie about a twofold rotation axis in the space group P2/c. Complex (II) forms a two-dimensional coordination polymer containing tetrahedrally coordinated Cu^I atoms, and complex (III) forms a one-dimensional coordination polymer containing five-coordinate square-pyramidal Cu^I atoms.

Formula: C₄H₆N₁₀, [Cu₂Cl₂(C₄H₆N₁₀)] and [CuCl(C₄H₆N₁₀)]


	Structure factor file (CIF format) (71.8 kbytes) [ doi:10.1107/S0108270106013199/gd3013Isup2.hkl ] Contains datablock I

	Structure factor file (CIF format) (67.7 kbytes) [ doi:10.1107/S0108270106013199/gd3013IIsup3.hkl ] Contains datablock absg

	Structure factor file (CIF format) (74.8 kbytes) [ doi:10.1107/S0108270106013199/gd3013IIIsup4.hkl ] Contains datablock l02

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