Acta Crystallographica Section C

Crystal Structure Communications

Volume 63, Part 3 (March 2007)

metal-organic compounds

bm3024 scheme

Acta Cryst. (2007). C63, m101-m104 [ doi:10.1107/S0108270107004970 ]

Bis(1-phenylethylammonium) hexachloridostannate(IV) and bis(2-phenylethylammonium) hexachloridostannate(IV)

D. G. Billing, A. Lemmerer and M. Rademeyer

Abstract: The crystal structures of the two isomers bis(1-phenylethylammonium) hexachloridostannate(IV) and bis(2-phenylethylammonium) hexachloridostannate(IV), both (C₈H₁₂N)₂[SnCl₆], exhibit alternating organic and inorganic layers, which interact via N-HCl hydrogen bonding. The inorganic layer contains an extended two-dimensional hydrogen-bonded sheet. The Sn atom in the 1-phenylethylammonium salt lies on an inversion centre.

Formula: Two isomers of (C₈H₁₂N)₂[SnCl₆]


	Structure factor file (CIF format) (107.3 kbytes) [ doi:10.1107/S0108270107004970/bm3024Isup2.hkl ] Contains datablock I

	Structure factor file (CIF format) (199.7 kbytes) [ doi:10.1107/S0108270107004970/bm3024IIsup3.hkl ] Contains datablock II

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