Acta Cryst. (2007). C63, m101-m104 [ doi:10.1107/S0108270107004970 ]
Abstract: The crystal structures of the two isomers bis(1-phenylethylammonium) hexachloridostannate(IV) and bis(2-phenylethylammonium) hexachloridostannate(IV), both (C8H12N)2[SnCl6], exhibit alternating organic and inorganic layers, which interact via N-HCl hydrogen bonding. The inorganic layer contains an extended two-dimensional hydrogen-bonded sheet. The Sn atom in the 1-phenylethylammonium salt lies on an inversion centre.
Formula: Two isomers of (C8H12N)2[SnCl6]
Structure factor file (CIF format) (107.3 kbytes)
Structure factor file (CIF format) (199.7 kbytes)
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