Acta Cryst. (2007). C63, i83-i85 [ doi:10.1107/S010827010704108X ]
Abstract: The structures of orthorhombic bis[pentaammineaquacobalt(III)] tetra-![[mu]](/logos/entities/mu_rmgif.gif)
2-fluorido-tetradecafluoridotrizirconium(IV) hexahydrate (space group Ibam), [Co(NH3)5(H2O)]2[Zr3F18]·6H2O, (I), and bis[hexaamminecobalt(III)] tetra-2-fluorido-tetradecafluoridotrizirconium(IV) hexahydrate (space group Pnna), [Co(NH3)6]2[Zr3F18]·6H2O, (II), consist of complex [Co(NH3)x(H2O)y]3+ cations with either m [in (I)] or 
and 2 [in (II)] symmetry, [Zr3F18]6- anionic chains located on sites with 222 [in (I)] or 2 [in (II)] symmetry, and water molecules.
Formula: [Co(NH3)5(H2O)]2[Zr3F18]·6H2O and [Co(NH3)6]2[Zr3F18]·6H2O
 |   Structure factor file (CIF format) (79.8 kbytes) |
| Structure factor file (CIF format) (154.0 kbytes) |
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