Acta Crystallographica Section C

Crystal Structure Communications

Volume 64, Part 1 (January 2008)

inorganic compounds

Acta Cryst. (2008). C64, i5-i8 [ doi:10.1107/S0108270107061963 ]

K₃Ga₂(PO₄)₃ and Na₃Ga(PO₄)₂

M. Beaurain, R. Astier, A. van der Lee and P. Armand

Abstract: The structures of tripotassium digallium tris(phosphate), K₃Ga₂(PO₄)₃, and trisodium gallium bis(phosphate), Na₃Ga(PO₄)₂, have different irregular one-dimensional alkali ion-containing channels along the a axis of the orthorhombic and triclinic unit cells, respectively. The anionic subsystems consist of vortex-linked PO₄ tetrahedra and GaO₄ tetrahedra or GaO₅ trigonal bipyramids in the first and second structure, respectively.

Formula: K₃Ga₂(PO₄)₃ and Na₃Ga(PO₄)₂


	Structure factor file (CIF format) (194.2 kbytes) [ doi:10.1107/S0108270107061963/iz3036Isup2.hkl ] Contains datablock I

	Structure factor file (CIF format) (217.6 kbytes) [ doi:10.1107/S0108270107061963/iz3036IIsup3.hkl ] Contains datablock II

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