Crystal Structure Communications

 

Acta Cryst. (2009). C65, i45-i47  [ doi:10.1107/S010827010902397X ]

Co_0.50VOPO₄·2H₂O

L. Meng, Y. Ma, X. Zhang and Y. Xu

Synopsis: The title cobalt vanadophosphate dihydrate contains flat layers of VO₅ and PO₄ polyhedra covalently linked by Co^II ions coordinated to vanadyl O atoms. This is believed to be the first example of a layered vanadophosphate bridged by a transition metal ion in this manner.

Formula: Co_0.50VOPO₄·2H₂O

Online 15 July 2009

 

Acta Cryst. (2009). C65, i48-i51  [ doi:10.1107/S0108270109021519 ]

Reinvestigation of Sr₂[Cu(OH)₆]

S. Sutovic, L. Karanovic and D. Poleti

Synopsis: Sr₂[Cu(OH)₆] crystallizes in the monoclinic system in the space group P2₁/n (No. 14). The crystal structure is built up from mutually isolated highly elongated Cu(OH)₆ octahedra and trigonal Sr(OH)₆ prisms, forming layers parallel to (110). The Cu(OH)₆ octahedra are connected into an infinite three-dimensional framework of hydrogen bonds.

Formula: Sr₂[Cu(OH)₆]

Online 18 July 2009

 

Acta Cryst. (2009). C65, i52-i53  [ doi:10.1107/S0108270109027188 ]

Na₁₀(Na,Mn)₇Mn₄₃(PO₄)₃₆: a new synthetic fillowite-type phosphate

F. Hatert, P. Keller, F. Lissner and T. Schleid

Synopsis: The title compound, Na₁₀(Na,Mn)₇Mn₄₃(PO₄)₃₆, has been synthesized hydrothermally. Its crystal structure is similar to that of natural fillowite-type phosphates and can be described as a hexagonal packing of three types of rods parallel to the c axis, which show an alternation of Mn, Na and P sites and lattice vacancies.

Formula: Na₁₀(Na,Mn)₇Mn₄₃(PO₄)₃₆

Online 22 July 2009

 

Acta Cryst. (2009). C65, i54-i56  [ doi:10.1107/S0108270109027218 ]

[CrBr₂(NH₃)₄][CrBr₄(NH₃)₂], a new chromium(III) complex

L. Stork, X. Liu, B. P. T. Fokwa and R. Dronskowski

Synopsis: The title compound, tetraamminedibromidochromium(III) diamminetetrabromidochromium(III), crystallizes in the space group P (Z = 1). The structure is composed of octahedral trans-[CrBr₂(NH₃)₄]⁺ cations and octahedral trans-[CrBr₄(NH₃)₂]^- anions adopting a distorted CsCl-type lattice.

Formula: [CrBr₂(NH₃)₄][CrBr₄(NH₃)₂]

Online 22 July 2009

 

Acta Cryst. (2009). C65, m273-m275  [ doi:10.1107/S010827010902438X ]

A new three-dimensional cobalt(II) coordination polymer with a 4-connected CdSO₄-like topology

Z.-L. Xu, Z.-G. Kong, S.-B. Sun and X.-Y. Wang

Formula: [Co(C₁₂H₈O₄)(H₂O)₂]

Online 7 July 2009

 

Acta Cryst. (2009). C65, m276-m278  [ doi:10.1107/S0108270109022331 ]

Poly[diaqua[-1,4-bis(imidazol-1-ylmethyl)benzene-²N³:N^3'](-trans-cyclohexane-1,4-carboxylato-²O¹:O⁴)manganese(II)]: a three-dimensional hydrogen-bonding -polonium net

Q.-W. Wang, X.-Y. Wang, M. Wang, B.-Y. Li and X.-Y. Ma

Formula: [Mn(C₈H₁₀O₄)(C₁₄H₁₄N₄)(H₂O)₂]

Online 7 July 2009

 

Acta Cryst. (2009). C65, m279-m283  [ doi:10.1107/S0108270109023968 ]

Bis(1,3,4-trimethylpyridinium) tetrachloridocuprate(II) and bis(1,3,4-trimethylpyridinium) tetrabromidocuprate(II): an examination of the A₂CuX₄ Fdd2 structure type

M. R. Bond

Formula: (C₈H₁₂N)₂[CuCl₄] and (C₈H₁₂N)₂[CuBr₄]

Online 7 July 2009

 

Acta Cryst. (2009). C65, m284-m286  [ doi:10.1107/S010827010902575X ]

The chiral helical structure of a copper(II) complex with a tridentate Schiff base ligand

W.-J. Shi

Formula: [Cu(C₉H₉N₂O₂)(H₂O)]ClO₄

Online 9 July 2009

 

Acta Cryst. (2009). C65, m287-m290  [ doi:10.1107/S0108270109021337 ]

Poly[hexaaquabis(₄-4-carboxybenzenesulfonato)bis(₃-4-carboxybenzenesulfonato)calcium(II)dipotassium(I)]

G. Prochniak and V. Videnova-Adrabinska

Formula: [CaK₂(C₇H₅O₅S)₄(H₂O)₆]

Online 9 July 2009

 

Acta Cryst. (2009). C65, m291-m295  [ doi:10.1107/S0108270109025311 ]

Two related lithium calixarene complexes, [p-tert-butylcalix[4]arene(OMe)(OH)₂(OLi)]₂·4MeCN and {p-tert-butylcalix[4]arene(OH)₂(OLi)[OLi(NCMe)₂]}₂·8MeCN, determined using synchrotron radiation

D. S. Lee, M. R. J. Elsegood, C. Redshaw and S. Zhan

Formula: [Li₂(C₄₅H₅₇O₄)₂]·4C₂H₃N and [Li₄(C₄₄H₅₄O₄)₂(C₂H₃N)₄]·8C₂H₃N

Online 9 July 2009

 

Acta Cryst. (2009). C65, m296-m298  [ doi:10.1107/S0108270109025293 ]

Diaqua(oxydiacetato-³O,O',O'')(pyridine-3-carboxamide-N¹)copper(II)

M. Perec and R. Baggio

Formula: [Cu(C₄H₄O₅)(C₆H₆N₂O)(H₂O)₂]

Online 9 July 2009

 

Acta Cryst. (2009). C65, m299-m301  [ doi:10.1107/S0108270109017831 ]

A monomeric gold(I) carbanion complex with an uncoordinated thioether: [2-(methylsulfanyl)phenyl](triphenylphosphine)gold(I)

D. Y. Melgarejo, G. M. Chiarella and J. P. Fackler

Formula: [Au(C₇H₇S)(C₁₈H₁₅P)]

Online 11 July 2009

 

Acta Cryst. (2009). C65, m302-m304  [ doi:10.1107/S0108270109024500 ]

Diaquatetrakis(tert-butyl isocyanide)cobalt(II) bis(perchlorate): an example of cobalt(II) coordinated by only four alkyl isocyanide ligands

C. A. L. Becker, R. P. Forbes and R. S. Black

Formula: [Co(C₅H₉N)₄(H₂O)₂](ClO₄)₂

Online 11 July 2009

 

Acta Cryst. (2009). C65, m305-m307  [ doi:10.1107/S010827010902695X ]

catena-Poly[[[(iminodiacetato-O)silver(I)]-₃-2-aminopyrimidine-³N¹:N²:N³] monohydrate]: a one-dimensional silver(I) coordination polymer with mixed ligands

D. Sun, G.-G. Luo, R.-B. Huang, N. Zhang and L.-S. Zheng

Formula: [Ag(C₄H₆NO₄)(C₄H₅N₃)]·H₂O

Online 15 July 2009

 

Acta Cryst. (2009). C65, m308-m310  [ doi:10.1107/S0108270109024445 ]

A novel metallo-organically templated pentaborate: acetato[N,N'-bis(2-aminoethyl)ethane-1,2-diamine]zinc(II) 4,4',6,6'-tetrahydroxy-2,2'-spirobi[cyclotriboroxane](1-)

S.-L. Wu, H.-X. Liu, X. Jiang, Z.-D. Shao and Y.-X. Liang

Formula: [Zn(C₂H₃O₂)(C₆H₁₈N₄)](B₅H₄O₁₀)

Online 18 July 2009

 

Acta Cryst. (2009). C65, m311-m313  [ doi:10.1107/S0108270109028005 ]

(Acetato-O)aqua(1H-imidazole-N³)(picolinato-²N,O)copper(II) 0.87-hydrate: a Z' > 1 structure

A.-C. Chamayou, C. Biswas, A. Ghosh and C. Janiak

Formula: [Cu(C₆H₄NO₂)(C₂H₃O₂)(C₃H₄N₂)(H₂O)]·0.87H₂O

Online 25 July 2009

 

Acta Cryst. (2009). C65, m314-m316  [ doi:10.1107/S0108270109027516 ]

(Acetato-O)[tris(3,5-dimethylpyrazol-1-yl-N²)hydroborato]zinc(II)

A. Beheshti, W. Clegg, S. H. Dale and R. Hyvadi

Formula: [Zn(C₁₅H₂₂BN₆)(C₂H₃O₂)]

Online 25 July 2009

 

Acta Cryst. (2009). C65, m317-m320  [ doi:10.1107/S0108270109027735 ]

A novel trinuclear zinc(II) cluster with a tetrahedral ZnO₄ core

O. Q. Munro, K. Gillham and M. P. Akerman

Formula: [Zn₃(C₁₁H₁₁NO₂)₂(C₂H₃O₂)₂(CH₄O)₂]

Online 25 July 2009

 

Acta Cryst. (2009). C65, m321-m324  [ doi:10.1107/S0108270109028571 ]

Three-dimensional framework structures: isomorphous bis(2,6-diamino-3,5-dibromopyridinium) tetrabromidometallate(II) salts with Cd^II and Mn^II

R. H. Al-Far, S. F. Haddad and B. F. Ali

Formula: (C₅H₆Br₂N₃)₂[CdBr₄] and (C₅H₆Br₂N₃)₂[MnBr₄]

Online 25 July 2009

 

Acta Cryst. (2009). C65, m325-m327  [ doi:10.1107/S0108270109027589 ]

catena-Poly[[bis(acetylacetonato-²O,O')cobalt(II)]--1,3-di-4-pyridylpropane-²N:N']: a one-dimensional coordination polymer capable of forming clathrates with prochiral aldehydes

A. Lennartson and M. Håkansson

Formula: [Co(C₅H₇O₂)₂(C₁₃H₁₄N₂)]

Online 30 July 2009

 

Acta Cryst. (2009). C65, m328-m330  [ doi:10.1107/S010827010902839X ]

The anionic coordination polymer {K₂[Pt^II₂Ag^I₈(2,2'-bipyridine)₂(O₂CCF₃)₁₄]}_n

Z. M. Hudson, Y. Sun, B. Ross, R.-Y. Wang and S. Wang

Formula: K₂[Pt₂Ag₈(C₂F₃O₂)₁₄(C₁₀H₈N₂)₂]

Online 30 July 2009

 

Acta Cryst. (2009). C65, o365-o370  [ doi:10.1107/S0108270109022203 ]

Structural comparisons between methylated and unmethylated nitrophenyl lophines

D. Yanover and M. Kaftory

Formula: C₂₁H₁₅N₃O₂, C₂₁H₁₅N₃O₂·C₂H₃N, C₂₁H₁₅N₃O₂·CH₄O, C₂₂H₁₇N₃O₂·CH₄O, C₂₂H₁₇N₃O₂ and C₂₂H₁₇N₃O₂

Online 7 July 2009

 

Acta Cryst. (2009). C65, o371-o373  [ doi:10.1107/S010827010902410X ]

N,N'-Bis(2-ammonioethyl)propane-1,3-diaminium tris(perchlorate) chloride

H. B. Szczesniak, V. Patroniak, W. Radecka-Paryzek and M. Kubicki

Formula: C₇H₂₄N₄⁴⁺·3ClO₄^-·Cl^-

Online 7 July 2009

 

Acta Cryst. (2009). C65, o374-o376  [ doi:10.1107/S0108270109025566 ]

4-(2-Fluorophenyl)-6-(1H-indol-1-yl)-3-methyl-1-phenyl-1H-pyrazolo[3,4-b]pyridine-5-carbonitrile: a chain of rings built from N-HN, C-HN and C-H(arene) hydrogen bonds

J. Quiroga, A. Sánchez, J. Cobo and C. Glidewell

Formula: C₂₈H₁₈FN₅

Online 9 July 2009

 

Acta Cryst. (2009). C65, o377-o380  [ doi:10.1107/S0108270109025451 ]

2-Oxo-2-phenyl-N-[(R)-1-phenylethyl]acetamide and N,N-dimethyl-2-(1-naphthyl)-2-oxoacetamide: possibility of Yang photocyclization in a crystal

J. Bakowicz and I. Turowska-Tyrk

Formula: C₁₆H₁₅NO₂ and C₁₄H₁₃NO₂

Online 9 July 2009

 

Acta Cryst. (2009). C65, o381-o384  [ doi:10.1107/S0108270109024457 ]

Polymorphism and phase transition behavior of 6,6'-bis(chloromethyl)-1,1',4,4'-tetramethyl-3,3'-(p-phenylenedimethylene)bis(piperazine-2,5-dione)

N. W. Polaske, G. S. Nichol and B. Olenyuk

Formula: Three polymorphs of C₂₂H₂₈Cl₂N₄O₄

Online 9 July 2009

 

Acta Cryst. (2009). C65, o385-o387  [ doi:10.1107/S0108270109025475 ]

N,N-Diethyl-N'-[(E)-4-pyridylmethylene]benzene-1,4-diamine: a combined X-ray and density functional theory study

R. W. Seidel, W. S. Sheldrick, T. M. Kolev and B. B. Koleva

Formula: C₁₆H₁₉N₃

Online 11 July 2009

 

Acta Cryst. (2009). C65, o388-o395  [ doi:10.1107/S0108270109025141 ]

Enantiotropic phase transition and twinning in 2,2,3,3,4,4-hexafluoropentane-1,5-diol

J.-M. Ha and V. Young

Formula: Four forms of C₅H₆F₆O₂

Online 11 July 2009

 

Acta Cryst. (2009). C65, o396-o399  [ doi:10.1107/S0108270109020551 ]

Weak intermolecular interactions in isomorphous 5-(2-chloroethoxy)-2,3-dihydro-1,4-benzodioxine and 5-(2-bromoethoxy)-2,3-dihydro-1,4-benzodioxine: bonding or nonbonding interactions

R. Kruszynski

Formula: C₁₀H₁₁ClO₃ and C₁₀H₁₁BrO₃

Online 11 July 2009

 

Acta Cryst. (2009). C65, o400-o403  [ doi:10.1107/S0108270109025682 ]

Similarities and differences between bis[2-(bromomethyl)phenyl] diselenide, bis[2-(chloromethyl)phenyl] diselenide and bis[2-(hydroxymethyl)phenyl] diselenide

A. Lari, F. Rominger and R. Gleiter

Formula: C₁₄H₁₂Br₂Se₂, C₁₄H₁₂Cl₂Se₂ and C₁₄H₁₄O₂Se₂

Online 15 July 2009

 

Acta Cryst. (2009). C65, o404-o405  [ doi:10.1107/S0108270109026511 ]

Triclosan

A. I. Ramos, S. S. Braga and F. A. Almeida Paz

Formula: C₁₂H₇Cl₃O₂

Online 15 July 2009

 

Acta Cryst. (2009). C65, o406-o409  [ doi:10.1107/S0108270109025165 ]

Structures of 1-hydrophenanthroimidazoles: building blocks in the synthesis of expanded-ring bis(imidazoles)

R. T. Stibrany and J. A. Potenza

Formula: C₁₅H₁₀N₂ and C₁₅H₈Br₂N₂·0.5H₂O

Online 15 July 2009

 

Acta Cryst. (2009). C65, o410-o413  [ doi:10.1107/S0108270109026390 ]

Supramolecular motifs in the first structures of organic carboxylate salts of 1-(diaminomethylene)thiourea (HATU)

M. Holynska and M. Kubiak

Formula: C₂H₇N₄S⁺·CHO₂^- and 2C₂H₇N₄S⁺·C₂O₄^2-·2H₂O

Online 15 July 2009

 

Acta Cryst. (2009). C65, o414-o418  [ doi:10.1107/S0108270109025724 ]

N-HO and O-HO hydrogen-bonded supramolecular networks in 4-chloroanilinium, 2-hydroxyanilinium and 3-hydroxyanilinium hydrogen phthalates

R. Jagan and K. Sivakumar

Formula: C₆H₇ClN⁺·C₈H₅O₄^- and two forms of C₆H₈NO⁺·C₈H₅O₄^-

Online 18 July 2009

 

Acta Cryst. (2009). C65, o419-o422  [ doi:10.1107/S0108270109027164 ]

Codeine dihydrogen phosphate hemihydrate

C. Langes, T. Gelbrich, U. J. Griesser and V. Kahlenberg

Formula: C₁₈H₂₂NO₃⁺·H₂PO₄^-·0.5H₂O

Online 18 July 2009

 

Acta Cryst. (2009). C65, o423-o430  [ doi:10.1107/S0108270109028017 ]

Eight 7-benzyl-3-tert-butyl-1-phenylpyrazolo[3,4-d]oxazines, encompassing structures containing no intermolecular hydrogen bonds, and hydrogen-bonded structures in one, two or three dimensions

J. C. Castillo, R. Abonía, J. Cobo and C. Glidewell

Formula: C₂₂H₂₅N₃O, C₂₃H₂₇N₃O, C₂₃H₂₇N₃O₂, C₂₃H₂₄F₃N₃O, C₂₂H₂₄N₄O₃, C₂₄H₂₉N₃O₃, C₂₃H₂₅N₃O₃ and C₂₅H₃₁N₃O₄

Online 30 July 2009