Sc_0.43(2)Rb₂Mo₁₅S₁₉, a partially Sc-filled variant of Rb₂Mo₁₅S₁₉

Sc_0.43Rb₂Mo₁₅S₁₉ constitutes a partially Sc-filled variant of Rb₂Mo₁₅S₁₉ containing an equal mixture of Mo₆S₈S₆ and Mo₉S₁₁S₆ cluster units. Extended Huckel tight-binding calculations provide an understanding of the variation in the Mo—Mo distances within the Mo clusters on the insertion of Sc.

Supra­molecular framework in catena-poly[[(nitrato-κO)silver(I)]-μ-(R,S)-2-(pyridin-4-ylsulfin­yl)pyrimidine-κ³N,O:N′]

Four Ni^II complexes with the new cyclam–methyl­imidazole ligand 1-[(1-methyl-1H-imidazol-2-yl)meth­yl]-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne

Chlorido(4,4′-dimeth­oxy-2,2′-bipyri­dine)(1,4,7-tri­methyl-1,4,7-tri­aza­cyclo­nona­ne)ruthenium(II) perchlorate aceto­nitrile disolvate and aqua­(4,4′-dimeth­oxy-2,2′-bi­pyridine)(1,4,7-tri­methyl-1,4,7-tri­aza­cyclo­nona­ne)ruthenium(II) bis­(per­chlorate) dihydrate

catena-Poly[[[(oxamide dioxime-κ²N,N′)copper(II)]-μ-L-tartrato-κ⁴O¹,O²:O³,O⁴] tetra­hydrate]: a chiral nanochannel framework hosting solvent water molecules

Synthesis and supra­molecular networks of 5,6-dioxo-1,10-phenanthroline-2,9-dicarb­oxy­lic acid dihydrate and its first coordination compound cis-di­aqua­chlorido(5,6-dioxo-1,10-phenanthroline-2,9-di­carb­oxy­lic acid-κ⁴O²,N,N′,O⁹)manganese(II) chloride dihydrate

Chiral crystals from an achiral mol­ecule: 4,6-di-O-benzyl-1,3-O-benzyl­idene-2-O-(4-meth­oxy­benzyl)-myo-5-inosose

Structural study of six cyclo­alkyl­ammonium cinnamate salt structures featuring one-dimensional columns and two-dimensional hydrogen-bonded networks

(2RS,4RS)-7-Fluoro-2-(2-phenyl­eth­yl)-2,3,4,5-tetra­hydro-1H-1,4-ep­oxy-1-benzazepine and (2RS,4RS)-7-chloro-2-(2-phenyl­eth­yl)-2,3,4,5-tetra­hydro-1H-1,4-ep­oxy-1-benzazepine are isomorphous but not strictly isostructural

2-Amino-6-meth­oxy-4-(4-methyl­anilino)-5-nitroso­pyrimidine and ethyl N-[4-(adamantan-1-yl­amino)-2-amino-5-nitroso­pyrimidin-6-yl]-3-amino­propionate: polarized electronic structures and hydrogen-bonded supra­molecular assembly in one and two dimensions

Analysis of geometric parameters and packing considerations for tri­phenylboroxine derivatives, with tris­(penta­fluoro­phen­yl)boroxine as an example

Redetermination of rifampicin penta­hydrate revealing a zwitterionic form of the anti­biotic