Acta Cryst. (2012). C68, m312-m316 [ doi:10.1107/S0108270112040589 ]
Abstract: The rigid organic linkers N-(4-bromophenylsulfonyl)dithiocarbimate(2-) and N-(4-iodophenylsulfonyl)dithiocarbimate(2-) crystallize with two potassium cations and two water molecules in their asymmetric units, forming the title coordination polymers, [K2(C7H4BrNO2S3)(H2O)2]n and [K2(C7H4INO2S3)(H2O)2]n. The anions and the water molecules link the potassium cations into broad two-dimensional networks, which are further linked by Khalide interactions.
Formula: [K2(C7H4BrNO2S3)(H2O)2] and [K2(C7H4INO2S3)(H2O)2]
Structure factor file (CIF format) (165.1 kbytes)
Structure factor file (CIF format) (182.0 kbytes)
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