Acta Cryst. (2012). C68, m347-m352 [ doi:10.1107/S0108270112043296 ]
Abstract: Bis{![[mu]](/logos/entities/mu_rmgif.gif)
-2-[bis(pyridin-2-ylmethyl)amino]acetato}bis[diaquamanganese(II)] bis(trifluoromethanesulfonate) monohydrate, [Mn2(C14H14N3O2)2(H2O)4](CF3O3S)2·H2O, (I), and bis{-3-[bis(pyridin-2-ylmethyl)amino]propionato}bis[aquamanganese(II)] bis(trifluoromethanesulfonate) dihydrate, [Mn2(C15H16N3O2)2(H2O)2](CF3O3S)2·2H2O, (II), form binuclear seven-coordinate complexes. Oxidation of (II) with ammonium hexanitratocerate(IV), (NH4)2[Ce(NO3)6], gave the oxide-bridged dimanganese(IV) complex di--oxido-bis(bis{3-[bis(pyridin-2-ylmethyl)amino]propionato}manganese(IV)) bis[triaquatetranitratocerate(IV)], [Mn2O2(C15H16N3O2)2][Ce(NO3)4(H2O)3]2, (III). The manganese complexes in (II) and (III) sit on a site of 
symmetry.
Formula: [Mn2(C14H14N3O2)2(H2O)4](CF3O3S)2·H2O, [Mn2(C15H16N3O2)2(H2O)2](CF3O3S)2·2H2O and [Mn2O2(C15H16N3O2)2][Ce(NO3)4(H2O)3]2
 |   Structure factor file (CIF format) (344.4 kbytes) |
| Structure factor file (CIF format) (225.4 kbytes) |
| Structure factor file (CIF format) (247.7 kbytes) |
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