Acta Crystallographica Section C

Crystal Structure Communications

Volume 69, Part 6 (June 2013)

metal-organic compounds

Acta Cryst. (2013). C69, 601-605    [ doi:10.1107/S0108270113010913 ]

The coordination chemistry of two symmetric double-armed oxa­diazole-bridged organic ligands with copper salts

X.-W. Wu, M.-M. Xin, J.-P. Ma, Z.-H. Wu and Y.-B. Dong

Abstract: Two new symmetric double-armed oxa­diazole-bridged ligands, 4-methyl-{5-[5-methyl-2-(pyridin-3-yl­carbon­yl­oxy)­phen­yl]-1,3,4-oxa­diazol-2-yl}phenyl pyridine-3-carboxyl­ate (L1) and 4-methyl-{5-[5-methyl-2-(pyridin-4-yl­carbon­yl­oxy)­phen­yl]-1,3,4-oxa­diazol-2-yl}phenyl pyridine-4-carboxyl­ate (L2), were prepared by the reaction of 2,5-bis­(2-hy­droxy-5-methyl­phen­yl)-1,3,4-oxa­diazole with nicotinoyl chloride and iso­nicotinoyl chloride, respectively. Ligand L1 can be used as an organic clip to bind CuII cations and generate a mol­ecular complex, bis­(4-methyl-{5-[5-methyl-2-(pyridin-3-yl­carbon­yl­oxy)phen­yl]-1,3,4-oxa­diazol-2-yl}phenyl pyridine-3-carboxyl­ate)bis­(perchlorato)­copper(II), [Cu(ClO4)2(C28H20N4O5)2], (I). In com­pound (I), the CuII cation is located on an inversion centre and is hexa­coordinated in a distorted octa­hedral geometry, with the pyridine N atoms of two L1 ligands in the equatorial positions and two weakly coordinating perchlorate counter-ions in the axial positions. The two arms of the L1 ligands bend inward and converge at the CuII coordination point to give rise to a spirometallocycle. Ligand L2 binds CuI cations to generate a supra­molecule, diaceto­nitrile­di-[mu]3-iodido-di-[mu]2-iodido-bis­(4-methyl-{5-[5-methyl-2-(pyridin-4-yl­carbon­yl­oxy)­phen­yl]-1,3,4-oxa­diazol-2-yl}phenyl pyridine-4-carboxyl­ate)tetracopper(I), [Cu4I4(CH3CN)2(C28H20N4O5)2], (II). The asymmetric unit of (II) indicates that it contains two CuI atoms, one L2 ligand, one aceto­nitrile ligand and two iodide ligands. Both of the CuI atoms are four-coordinated in an approximately tetra­hedral environment. The molecule is centrosymmetric and the four I atoms and four CuI atoms form a rope-ladder-type [Cu4I4] unit. Discrete units are linked into one-dimensional chains through [pi]-[pi] inter­actions.

Formula: [Cu(ClO4)2(C28H20N4O5)2] and [Cu4I4(C2H3N)2(C28H20N4O5)2]

hkldisplay filedownload file

Structure factor file (CIF format) (249.9 kbytes)
[ doi:10.1107/S0108270113010913/ov3026Isup2.hkl ]
Contains datablock I

hkldisplay filedownload file

Structure factor file (CIF format) (279.7 kbytes)
[ doi:10.1107/S0108270113010913/ov3026IIsup3.hkl ]
Contains datablock II


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