Acta Crystallographica Section C

Crystal Structure Communications

Volume 69, Part 6 (June 2013)


metal-organic compounds



wq3029 scheme

Acta Cryst. (2013). C69, 581-583    [ doi:10.1107/S0108270113009049 ]

A novel hexairon cluster with one disulfide and two Ph2PCS3- ligands

Y.-C. Shi, H.-R. Cheng and D.-C. Cheng

Abstract: The title compound, hexadecacarbonylbis{[mu]3-[(diphenylphosphanyl)methanediidyl]sulfanido}-[mu]4-disulfido(2-)-hexairon(4 Fe-Fe), [Fe6(C13H10PS)2(S2)(CO)16], contains two inversion-related [Fe3(Ph2PCS)(CO)8] subclusters linked by an equatorial disulfide bond [S-S = 2.1490 (9) Å]. Each Ph2PCS3- ligand is coordinated to a triiron core in a [mu]3-[kappa]P:[kappa]2C:[kappa]2S fashion.

Formula: [Fe6(C13H10PS)2(S2)(CO)16]


moldisplay filedownload file

MDL mol file (9.0 kbytes)
[ doi:10.1107/S0108270113009049/wq3029Isup3.mol ]
Supplementary material


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