Acta Cryst. (2013). C69, 855-858 [ doi:10.1107/S0108270113017277 ]
Abstract: Details of the structures of two polymorphs of tris(ethylenediamine)cobalt(III) tetrathioantimonate(V), [Co(C2H8N2)3][SbS4], are reported. The first polymorph crystallizes in the orthorhombic space group Pna21, whereas the second polymorph belongs to the tetragonal space group P42bc. Both structures contain octahedral [Co(en)3]3+ cations (en is ethylenediamine) and tetrahedral [SbS4]3- anions, which are interconnected via various N-HS hydrogen bonds to form two different types of three-dimensional network.
Formula: Two polymorphs of [Co(C2H8N2)3][SbS4]
Keywords: crystal structure; polymorphs; cobalt complexes; chalcogenides; thioantimonates.
Structure factor file (CIF format) (183.0 kbytes)
Structure factor file (CIF format) (185.6 kbytes)
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