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Acta Cryst. (2013). C69, 851-854  [ doi:10.1107/S0108270113018118 ]

Bis{2-[(phenyl­imino)­eth­yl]-1H-pyrrol-1-ido-[kappa]2N,N'}nickel(II): a supra­molecular structure formed by C-H...[pi] hydrogen bonds

B.-Y. Su, J.-X. Wang, X. Liu and Q.-D. Li

Synopsis: The title complex is composed of two deprotonated N,N'-bidentate 2-[(phenyl­imino)­ethyl]-1H-pyrrol-1-ide ligands around a central NiII cation, with the pyrrolide rings and imine groups lying trans to each other. Mol­ecules are linked into simple chains by two C-H...[pi] hydrogen bonds, one of which is inter­molecular with a phenyl [beta]-C atom as donor, while the other is intra­molecular with a pyrrole [beta]-C atom as donor.

Formula: [Ni(C12H11N2)2]


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