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Acta Cryst. (2013). C69, 862-867  [ doi:10.1107/S0108270113018465 ]

Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexa­methyl-1,4,8,11-tetra­aza­cyclotetra­decane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl

S. Yasmin, S. Suarez, F. Doctorovich, T. G. Roy and R. Baggio

Synopsis: The three title transition-metal complexes display a distorted 4+2 octahedral environment for the cation, with the macrocycle defining the base. The effect of the different axial ligands in the intra- and intermolecular hydrogen bonding is discussed.

Formula: [Cu(ClO4)2(C18H40N4)], [Zn(NO3)2(C18H40N4)] and [CuCl(C18H40N4)(H2O)]Cl


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