Acta Cryst. (2013). C69, 904-909 [ doi:10.1107/S0108270113017629 ]
Abstract: In bis(2-aminoanilinum) fumarate, 2C6H9N2+·C4H2O42-, (I), the asymmetric unit consists of two aminoanilinium cations and one fumarate dianion, whereas in 3-methylanilinium hydrogen fumarate, C7H10N+·C4H3O4-, (II), and 4-chloroanilinium hydrogen fumarate, C6H7ClN+·C4H3O4-, (III), the asymmetric unit contains two symmetry-independent hydrogen fumate anions and anilinium cations with a slight difference in their geometric parameters; the two salts are isostructural. In (II) and (III), the carboxylic acid H atoms of the anions are disordered across both ends of the anion, with equal site occupancies of 0.50. Both the 4-chloroanilinium cations of (III) are disordered over two orientations with major occupancies fixed at 0.60 in each case. The hydrogen fumarate anions of (II) and (III) form one-dimensional anionic chains linked through O-HO hydrogen bonds. Salts (II) and (III) form two-dimensional supramolecular sheets built from R44(16), R44(18), R55(25) and C22(14) motifs extending parallel to the (010) plane, whereas in (I), an (010) sheet is formed built from two R43(13) motifs, two R22(9) motifs and an R44(18) motif.
Formula: 2C6H9N2+·C4H2O42- and two analogues
Keywords: crystal structure; hydrogen bonding; fumarate salts.
Structure factor file (CIF format) (167.2 kbytes)
Structure factor file (CIF format) (328.6 kbytes)
Structure factor file (CIF format) (261.2 kbytes)
To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.
The download button will force most browsers to prompt for a file name to store the data on your hard disk.
Where possible, images are represented by thumbnails.
Copyright © International Union of Crystallography