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Acta Cryst. (2013). C69, 1017-1021  [ doi:10.1107/S0108270113019963 ]

One-dimensional CuI and AgI ladder-like coordination polymers supported by 2-ethyl-1-(pyridin-3-ylmeth­yl)-1H-benzimidazole

L. Gui, G. Liang, H. Zou and Z. Hou

Synopsis: In CuI and AgI ladder-like coordination polymers, two metal ions are linked by two 2-ethyl-1-(pyridin-3-ylmeth­yl)-1H-benzimidazole ligands (bep) to form a centrosymmetric 18-membered M2(bep)2 metallacycle, while adjacent M2(bep)2 metallacycles are further inter­linked by another two bep ligands resulting in a ladder-like array.

Formula: [Cu(C15H15N3)2]BF4·C2H3N and [Ag(C15H15N3)2]ClO4·CH4O

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