Acta Crystallographica Section C

Crystal Structure Communications

Volume 69, Part 9 (September 2013)


organic compounds



yf3046 scheme

Acta Cryst. (2013). C69, 1039-1042    [ doi:10.1107/S0108270113020246 ]

(E)-3-tert-Butyl-4-(4-chlorobenzyl)-N-(4-chlorobenzylidene)-1-phenyl-1H-pyrazol-5-amine: sheets built from [pi]-stacked hydrogen-bonded dimers

J. Quiroga, D. Pantoja, J. Cobo and C. Glidewell

Abstract: The title compound, C27H25Cl2N3, is an unexpected but high-yield product from the microwave-mediated reaction between 3-tert-butyl-N-4-chlorobenzyl-1-phenyl-1H-pyrazol-5-amine and 4-chlorobenzaldehyde. Inversion-related pairs of molecules are linked by C-H...[pi](arene) hydrogen bonds to form cyclic centrosymmetric dimers, and dimers of this type are linked into sheets by two independent [pi]-[pi] stacking interactions.

Formula: C27H25Cl2N3

Keywords: crystal structure; [pi]-stacked hydrogen-bonded dimers; pyrazolamines; microwave-mediated reactions.


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[ doi:10.1107/S0108270113020246/yf3046Isup3.cml ]
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