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Acta Cryst. (2013). C69, 939-942  [ doi:10.1107/S0108270113015953 ]

A tris(pyrazolyl)borate rhodium phosphite complex that undergoes an Arbusov-like rearrangement

Y. Jiao, W. W. Brennessel and W. D. Jones

Synopsis: In the presence of difluoromethane in pentane solvent, the scorpionate complex Tp'Rh[P(OMe)3](Me)H loses methane to give a product in which the phosphine O-Me bond is cleaved.

Formula: [Rh2(CH3)2(C2H6O3P)2(C15H22BN6)2]


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