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Acta Cryst. (2013). C69, 968-971  [ doi:10.1107/S0108270113017022 ]

Cobalt azide complexes with a tris(carbene)borate ligand scaffold

J. J. Scepaniak, C. G. Margarit, R. P. Bontchev and J. M. Smith

Synopsis: One electron oxidation of a four-coordinate tris(carbene)borate cobalt(II) azide complex yields a five-coordinate cobalt(III) bis(azide).

Formula: [Co(C27H38BN6)(N3)] and [Co(C27H38BN6)(N3)2]

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