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Acta Cryst. (2013). C69, 963-967  [ doi:10.1107/S0108270113016648 ]

Gallium hydride and monovalent indium compounds that feature tris­(pyrazol­yl)hydro­borate ligands

K. Yurkerwich, Y. Rong and G. Parkin

Synopsis: Tris(pyrazolyl)hydroborate ligation has been used to isolate trivalent gallium hydride and monovalent indium complexes, namely {[TpBut,Me]GaH}[GaCl4], [TpMe2]In and [TpBut,Me]In, which have been structurally characterized by single-crystal X-ray diffraction.

Formula: [In(C15H22BN6)], [In(C24H40BN6)] and [Ga(C24H40BN6)H][GaCl4]

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