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Acta Cryst. (2013). C69, 1120-1123  [ doi:10.1107/S0108270113023135 ]

Aluminium(III) amidinates formed from reactions of `AlCl' with lithium amidinates

D. H. Mayo, Y. Peng, P. Zavalij, K. H. Bowen and B. W. Eichhorn

Synopsis: The reaction of metastable aluminum monochloride in the presence of lithium amidinates results in the formation of AlIII amidinates upon heating. Two novel heteroleptic AlIII bis-amidinate chlorides and one homoleptic AlIII tris-amidinate complex are reported.

Formula: [Al(C13H19N2)3], [Al(C13H19N2)2Cl] and [Al(C19H27N2)2Cl]·0.675C4H8O


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