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Acta Cryst. (2013). C69, 1112-1115  [ doi:10.1107/S0108270113023007 ]

(Hexa­fluoro­silicato-[kappa]2F,F')bis­(1,10-phenanthroline-[kappa]2N,N')zinc(II) methanol monosolvate

R. W. Seidel, C. Dietz, J. Breidung, R. Goddard and I. M. Oppel

Synopsis: The title compound contains a neutral heteroleptic tris-chelate ZnII complex, viz. [Zn(SiF6)(phen)2] (phen is 1,10-phenanthroline), exhibiting approximate mol­ecular C2 point-group symmetry, and represents the first structurally characterized example of a ZnII complex bearing a bidentate-bound hexa­fluoro­silicate ligand.

Formula: [Zn(SiF6)(C12H8N2)2]·CH4O


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